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First example of a click-reaction on the aminate copper complexes: effect of reaction parameters

Igor Vladimirovich Esarev 1
Igor Vladimirovich Esarev
, 
Vladislav V Gurzhiy 2
Vladislav V Gurzhiy
, 
Artem Alexandrovich Selyutin 2
Artem Alexandrovich Selyutin
, 
Anastasia Vladimirovna Laptenkova 2
Anastasia Vladimirovna Laptenkova
, 
Andrey Igorevich Poddel'sky 3
Andrey Igorevich Poddel'sky
, 
Nicolay Leonidovich Medvedskiy 1
Nicolay Leonidovich Medvedskiy
, 
Alexander Ivanovich Ponyaev 1
Alexander Ivanovich Ponyaev
, 
Rostislav Evgen'evich Trifonov 1, 2
Rostislav Evgen'evich Trifonov
, 
Alexey Vladimirovich Eremin 1, 4
Alexey Vladimirovich Eremin
10.1016/j.mencom.2018.11.014
Published 2018-11-01
Communication , Volume 28, Issue 6, 606-608
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Esarev I. V. et al. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
GOST all authors (up to 50) Copy
Esarev I. V., Gurzhiy V. V., Selyutin A. A., Laptenkova A. V., Poddel'sky A. I., Medvedskiy N. L., Ponyaev A. I., Trifonov R. E., Eremin A. V. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.014
TI - First example of a click-reaction on the aminate copper complexes: effect of reaction parameters
T2 - Mendeleev Communications
AU - Esarev, Igor Vladimirovich
AU - Gurzhiy, Vladislav V
AU - Selyutin, Artem Alexandrovich
AU - Laptenkova, Anastasia Vladimirovna
AU - Poddel'sky, Andrey Igorevich
AU - Medvedskiy, Nicolay Leonidovich
AU - Ponyaev, Alexander Ivanovich
AU - Trifonov, Rostislav Evgen'evich
AU - Eremin, Alexey Vladimirovich
PY - 2018
DA - 2018/11/01
PB - Mendeleev Communications
SP - 606-608
IS - 6
VL - 28
ER -
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@article{2018_Esarev,
author = {Igor Vladimirovich Esarev and Vladislav V Gurzhiy and Artem Alexandrovich Selyutin and Anastasia Vladimirovna Laptenkova and Andrey Igorevich Poddel'sky and Nicolay Leonidovich Medvedskiy and Alexander Ivanovich Ponyaev and Rostislav Evgen'evich Trifonov and Alexey Vladimirovich Eremin},
title = {First example of a click-reaction on the aminate copper complexes: effect of reaction parameters},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.014},
number = {6},
pages = {606--608},
doi = {10.1016/j.mencom.2018.11.014}
}
MLA
Cite this
MLA Copy
Esarev, Igor Vladimirovich, et al. “First example of a click-reaction on the aminate copper complexes: effect of reaction parameters.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 606-608. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.014.

Abstract

The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

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