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Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments

, 
Nadezhda Sergeevna Smirnova 1
Nadezhda Sergeevna Smirnova
,  , 
Galina Nikolaevna Baeva 1
Galina Nikolaevna Baeva
, 
Galina Olegovna Bragina 1
Galina Olegovna Bragina
, 
Andrey Valerievich Bukhtiyarov 2
Andrey Valerievich Bukhtiyarov
, 
Igor P Prosvirin 2
Igor P Prosvirin
, 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2018.11.013
Published 2018-11-01
Communication , Volume 28, Issue 6, 603-605
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Mashkovsky I. S. et al. Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 603-605.
GOST all authors (up to 50) Copy
Mashkovsky I. S., Smirnova N. S., Markov P. V., Baeva G. N., Bragina G. O., Bukhtiyarov A. V., Prosvirin I. P., Stakheev A. Y. Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 603-605.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.013
TI - Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments
T2 - Mendeleev Communications
AU - Mashkovsky, Igor' Sergeevich
AU - Smirnova, Nadezhda Sergeevna
AU - Markov, Pavel Viktorovich
AU - Baeva, Galina Nikolaevna
AU - Bragina, Galina Olegovna
AU - Bukhtiyarov, Andrey Valerievich
AU - Prosvirin, Igor P
AU - Stakheev, Aleksandr Yurevich
PY - 2018
DA - 2018/11/01
PB - Mendeleev Communications
SP - 603-605
IS - 6
VL - 28
ER -
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@article{2018_Mashkovsky,
author = {Igor' Sergeevich Mashkovsky and Nadezhda Sergeevna Smirnova and Pavel Viktorovich Markov and Galina Nikolaevna Baeva and Galina Olegovna Bragina and Andrey Valerievich Bukhtiyarov and Igor P Prosvirin and Aleksandr Yurevich Stakheev},
title = {Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.013},
number = {6},
pages = {603--605},
doi = {10.1016/j.mencom.2018.11.013}
}
MLA
Cite this
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Mashkovsky, Igor' Sergeevich, et al. “Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 603-605. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.013.

Abstract

The in situ DRIFT-CO and XPS data demonstrated that the mild oxidation of PdIn intermetallic nanoparticles results in the partial oxidation of an In component and the trans-formation of isolated Pd1 sites to Pdn multiatomic ones thus enhancing PdIn activity in the liquid-phase hydrogenation of diphenylacetylene without sacrificing the alkene selectivity.

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