Home / Publications / Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides

Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides

Pavel Anatol'evich Volkov 1
Pavel Anatol'evich Volkov
, 
Nina Ivanovna Ivanova 1
Nina Ivanovna Ivanova
, 
Kseniya Olegovna Khrapova 1
Kseniya Olegovna Khrapova
, 
Anton Alekseevich Telezhkin 1
Anton Alekseevich Telezhkin
, 
Tatyana Nikolaevna Borodina 1
Tatyana Nikolaevna Borodina
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2018.11.005
Published 2018-11-01
Communication , Volume 28, Issue 6, 582-583
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Volkov P. A. et al. Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 582-583.
GOST all authors (up to 50) Copy
Volkov P. A., Ivanova N. I., Khrapova K. O., Telezhkin A. A., Borodina T. N., Gusarova N. K., Trofimov B. A. Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 582-583.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.005
TI - Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides
T2 - Mendeleev Communications
AU - Volkov, Pavel Anatol'evich
AU - Ivanova, Nina Ivanovna
AU - Khrapova, Kseniya Olegovna
AU - Telezhkin, Anton Alekseevich
AU - Borodina, Tatyana Nikolaevna
AU - Gusarova, Nina Kuzminichna
AU - Trofimov, Boris Aleksandrovich
PY - 2018
DA - 2018/11/01
PB - Mendeleev Communications
SP - 582-583
IS - 6
VL - 28
ER -
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@article{2018_Volkov,
author = {Pavel Anatol'evich Volkov and Nina Ivanovna Ivanova and Kseniya Olegovna Khrapova and Anton Alekseevich Telezhkin and Tatyana Nikolaevna Borodina and Nina Kuzminichna Gusarova and Boris Aleksandrovich Trofimov},
title = {Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.005},
number = {6},
pages = {582--583},
doi = {10.1016/j.mencom.2018.11.005}
}
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Volkov, Pavel Anatol'evich, et al. “Solvent-free synthesis of 4-chalcogenophosphorylpyridines via \( \mathrm{S_N^H Ar} \) reaction of pyridines with secondary phosphine chalcogenides.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 582-583. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.005.
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Abstract

Solvent- and catalyst-free synthesis of 4-chalcogenophosphorylpyridines by oxidative regioselective cross-coupling of pyridines with secondary phosphine chalcogenides using 1,3-diphenylprop-2-yn-1-one as a trigger and oxidant under mild conditions 70-75 °C, 5.5-7~h is reported.

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