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A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines

Kirill Evgenievich Metlushka 1
Kirill Evgenievich Metlushka
Dilyara Nurgalievna Sadkova 1
Dilyara Nurgalievna Sadkova
Kristina Aleksandrovna Nikitina 1
Kristina Aleksandrovna Nikitina
Zilya Rafikovna Yamaleeva 1
Zilya Rafikovna Yamaleeva
Kamil A. Ivshin 1, 2
Kamil A. Ivshin
Olga Nikolaevna Kataeva 1
Olga Nikolaevna Kataeva
Vladimir Alekseevich Alfonsov 1
Vladimir Alekseevich Alfonsov
Published 2018-11-01
CommunicationVolume 28, Issue 6, 579-581
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Metlushka K. E. et al. A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 579-581.
GOST all authors (up to 50) Copy
Metlushka K. E., Sadkova D. N., Nikitina K. A., Yamaleeva Z. R., Ivshin K. A., Kataeva O. N., Alfonsov V. A. A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 579-581.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.004
TI - A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines
T2 - Mendeleev Communications
AU - Metlushka, Kirill Evgenievich
AU - Sadkova, Dilyara Nurgalievna
AU - Nikitina, Kristina Aleksandrovna
AU - Yamaleeva, Zilya Rafikovna
AU - Ivshin, Kamil A.
AU - Kataeva, Olga Nikolaevna
AU - Alfonsov, Vladimir Alekseevich
PY - 2018
DA - 2018/11/01
PB - Mendeleev Communications
SP - 579-581
IS - 6
VL - 28
ER -
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@article{2018_Metlushka,
author = {Kirill Evgenievich Metlushka and Dilyara Nurgalievna Sadkova and Kristina Aleksandrovna Nikitina and Zilya Rafikovna Yamaleeva and Kamil A. Ivshin and Olga Nikolaevna Kataeva and Vladimir Alekseevich Alfonsov},
title = {A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.004},
number = {6},
pages = {579--581},
doi = {10.1016/j.mencom.2018.11.004}
}
MLA
Cite this
MLA Copy
Metlushka, Kirill Evgenievich, et al. “A new synthetic route to chiral 3-aryl-5-ethyl-1,4,2-oxazaphosphorines.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 579-581. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.004.

Abstract

Diastereoselective synthesis of racemic and enantiopure 3-aryl-5-ethyl-1,4,2-oxazaphosphorines, including those bearing phenolic hydroxyl groups in the exocyclic aromatic fragment, was implemented by the reaction of imines derived from (±)-and (R)-(−)-2-aminobutan-1-ol and (hydroxy)benzaldehydes with triethyl phosphite and trifluoroacetic acid, followed by the one-pot dealkylation of the intermediate esters.

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