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Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene

Sergei Evgen'evich Boganov 1
Sergei Evgen'evich Boganov
, 
Vladimir Mordkovich Promyslov 1
Vladimir Mordkovich Promyslov
, 
Stanislav Sergeyevich Rynin 1
Stanislav Sergeyevich Rynin
, 
Irina Vital'evna Krylova 1
Irina Vital'evna Krylova
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2018.11.002
Published 2018-11-01
Communication , Volume 28, Issue 6, 574-576
7
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Boganov S. E. et al. Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 574-576.
GOST all authors (up to 50) Copy
Boganov S. E., Promyslov V. M., Rynin S. S., Krylova I. V., Egorov M. P. Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 574-576.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.002
TI - Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene
T2 - Mendeleev Communications
AU - Boganov, Sergei Evgen'evich
AU - Promyslov, Vladimir Mordkovich
AU - Rynin, Stanislav Sergeyevich
AU - Krylova, Irina Vital'evna
AU - Egorov, Mikhail Petrovich
PY - 2018
DA - 2018/11/01
PB - Mendeleev Communications
SP - 574-576
IS - 6
VL - 28
ER -
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@article{2018_Boganov,
author = {Sergei Evgen'evich Boganov and Vladimir Mordkovich Promyslov and Stanislav Sergeyevich Rynin and Irina Vital'evna Krylova and Mikhail Petrovich Egorov},
title = {Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.002},
number = {6},
pages = {574--576},
doi = {10.1016/j.mencom.2018.11.002}
}
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Boganov, Sergei Evgen'evich, et al. “Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 574-576. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.11.002.

Abstract

A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate a photochemical version of this interaction resulting in the formation of both 1,1-dichloro-1-silacyclopent-3-ene and 1,1-dichloro-2-vinylsilirane in contrast to the thermal reaction giving only the first of these products.

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