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Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands

Ksenia Vital'evna Tsys 1
Ksenia Vital'evna Tsys
, 
Maxim Gennad'evich Chegerev 1, 2
Maxim Gennad'evich Chegerev
, 
Georgy Konstantinovich Fukin 1
Georgy Konstantinovich Fukin
, 
Aleksandr Vladimirovich Piskunov 1
Aleksandr Vladimirovich Piskunov
10.1016/j.mencom.2018.09.026
Published 2018-09-07
Communication , Volume 28, Issue 5, 527-529
29
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Tsys K. V. et al. Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 527-529.
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Tsys K. V., Chegerev M. G., Fukin G. K., Piskunov A. V. Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 527-529.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.026
TI - Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands
T2 - Mendeleev Communications
AU - Tsys, Ksenia Vital'evna
AU - Chegerev, Maxim Gennad'evich
AU - Fukin, Georgy Konstantinovich
AU - Piskunov, Aleksandr Vladimirovich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 527-529
IS - 5
VL - 28
ER -
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@article{2018_Tsys,
author = {Ksenia Vital'evna Tsys and Maxim Gennad'evich Chegerev and Georgy Konstantinovich Fukin and Aleksandr Vladimirovich Piskunov},
title = {Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.026},
number = {5},
pages = {527--529},
doi = {10.1016/j.mencom.2018.09.026}
}
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Tsys, Ksenia Vital'evna, et al. “Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 527-529. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.026.

Abstract

The reaction of dilithium salts of 4,6-di-tert-butyl-N-(R)-o-aminophenols with PbCl2 leads to the formation of new O,N-heterocyclic plumbylenes [R is But or dipp (2,6-diiso-propylphenyl)]. Both compounds possess dimeric structure in crystals according to the X-ray analysis of a single crystal. The formation of unstable paramagnetic plumbylene was detected during an oxidation of 4,6-di-tert-butyl-N-(tert-butyl)-o-aminophenolatolead(II) with HgBr2.

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