Home / Publications / Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene

Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene

Elena Yur'evna Schmidt 1, 2
Elena Yur'evna Schmidt
, 
Ivan A. Bidusenko 1
Ivan A. Bidusenko
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2018.09.021
Published 2018-09-07
Communication , Volume 28, Issue 5, 513-514
7
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Schmidt E. Y. et al. Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 513-514.
GOST all authors (up to 50) Copy
Schmidt E. Y., Bidusenko I. A., Ushakov I. A., Trofimov B. A. Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 513-514.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.021
TI - Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene
T2 - Mendeleev Communications
AU - Schmidt, Elena Yur'evna
AU - Bidusenko, Ivan A.
AU - Ushakov, Igor Alekseevich
AU - Trofimov, Boris Aleksandrovich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 513-514
IS - 5
VL - 28
ER -
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@article{2018_Schmidt,
author = {Elena Yur'evna Schmidt and Ivan A. Bidusenko and Igor Alekseevich Ushakov and Boris Aleksandrovich Trofimov},
title = {Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.021},
number = {5},
pages = {513--514},
doi = {10.1016/j.mencom.2018.09.021}
}
MLA
Cite this
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Schmidt, Elena Yur'evna, et al. “Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 513-514. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.021.

Abstract

Nickel-catalyzed low pressure hydrogenation of 1,5-diaryl-7-methylidene-6,8-dioxabicyclo[3.2.1]octanes proceeds chemo-specifically at the double bond and brings about mostly 1R*,3R*,5S*,7R* diastereomers.

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