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Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety

Vladimir Anatol'evich D'yakonov 1
Vladimir Anatol'evich D'yakonov
, 
Ilgiz Ilshatovich Islamov 1
Ilgiz Ilshatovich Islamov
, 
Èlvina Maratovna Khusainova 1
Èlvina Maratovna Khusainova
, 
10.1016/j.mencom.2018.09.017
Published 2018-09-07
Communication , Volume 28, Issue 5, 503-504
10
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D'yakonov V. A. et al. Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 503-504.
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D'yakonov V. A., Islamov I. I., Khusainova È. M., Dzhemilev U. M. Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 503-504.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.017
TI - Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety
T2 - Mendeleev Communications
AU - D'yakonov, Vladimir Anatol'evich
AU - Islamov, Ilgiz Ilshatovich
AU - Khusainova, Èlvina Maratovna
AU - Dzhemilev, Usein Memetovich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 503-504
IS - 5
VL - 28
ER -
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@article{2018_D'yakonov,
author = {Vladimir Anatol'evich D'yakonov and Ilgiz Ilshatovich Islamov and Èlvina Maratovna Khusainova and Usein Memetovich Dzhemilev},
title = {Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.017},
number = {5},
pages = {503--504},
doi = {10.1016/j.mencom.2018.09.017}
}
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D'yakonov, Vladimir Anatol'evich, et al. “Original catalytic synthesis of macrodiolides containing a 1Z,5Z-diene moiety.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 503-504. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.017.

Abstract

Macrodiolides containing a 1Z,5Z-diene moiety were obtained with high selectivity (>98%) and in good yields (59–70%) by the Cu(OTf)2-catalyzed intermolecular esterification of aliphatic α,ω-dicarboxylic acids with tetradeca-5Z,9Z-diene- 1,14-diol. This diol was accessed by homocyclomagnesiation of hepta-5,6-dien-1-ol tetrahydropyranyl ether using EtMgBr/Mg reagent system and Cp2TiCl2 catalyst.

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