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Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones

Liliya Khalitovna Faizullina 1
Liliya Khalitovna Faizullina
, 
Yuliya Sergeevna Galimova 1
Yuliya Sergeevna Galimova
, 
Yuliya Aleksandrovna Khalilova 1
Yuliya Aleksandrovna Khalilova
, 
Shamil Mubarakovich Salikhov 1
Shamil Mubarakovich Salikhov
, 
Farid Abdullovich Valeev 1
Farid Abdullovich Valeev
10.1016/j.mencom.2018.09.009
Published 2018-09-07
Communication , Volume 28, Issue 5, 482-484
4
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Faizullina L. K. et al. Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 482-484.
GOST all authors (up to 50) Copy
Faizullina L. K., Galimova Y. S., Khalilova Y. A., Salikhov S. M., Valeev F. A. Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 482-484.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.009
TI - Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones
T2 - Mendeleev Communications
AU - Faizullina, Liliya Khalitovna
AU - Galimova, Yuliya Sergeevna
AU - Khalilova, Yuliya Aleksandrovna
AU - Salikhov, Shamil Mubarakovich
AU - Valeev, Farid Abdullovich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 482-484
IS - 5
VL - 28
ER -
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@article{2018_Faizullina,
author = {Liliya Khalitovna Faizullina and Yuliya Sergeevna Galimova and Yuliya Aleksandrovna Khalilova and Shamil Mubarakovich Salikhov and Farid Abdullovich Valeev},
title = {Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.009},
number = {5},
pages = {482--484},
doi = {10.1016/j.mencom.2018.09.009}
}
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Faizullina, Liliya Khalitovna, et al. “Aldol-type transformations of levoglucosenone-derived medium-sized keto lactones.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 482-484. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.009.

Abstract

Action of bases on levoglucosenone-derived 6-oxononan-9-olide and 7-oxodecan-10-olide causes the transannular reaction of the aldol type affording stable 2-acylcyclopent-1-en-1-ol and 2-acylcyclohex-1-en-1-ol, respectively. The lower homologue, 5-oxooctan-8-olide derivative, under the similar conditions gives a complex mixture of products, which may be explained by the poor stability of the intermediate 2-acyl-cyclobut-1-en-1-ol.

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