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Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene

Ilya Eduardovich Nifant'ev 1, 2
Ilya Eduardovich Nifant'ev
, 
Alexander Andreevich Vinogradov 1
Alexander Andreevich Vinogradov
, 
Alexey Andreevich Vinogradov 1
Alexey Andreevich Vinogradov
, 
Andrei Viktorovich Churakov 3
Andrei Viktorovich Churakov
, 
Pavel Vasil'evich Ivchenko 1, 2
Pavel Vasil'evich Ivchenko
10.1016/j.mencom.2018.09.004
Published 2018-09-07
Communication , Volume 28, Issue 5, 467-469
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Nifant'ev I. E. et al. Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 467-469.
GOST all authors (up to 50) Copy
Nifant'ev I. E., Vinogradov A. A., Vinogradov A. A., Churakov A. V., Ivchenko P. V. Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 467-469.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.004
TI - Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene
T2 - Mendeleev Communications
AU - Nifant'ev, Ilya Eduardovich
AU - Vinogradov, Alexander Andreevich
AU - Vinogradov, Alexey Andreevich
AU - Churakov, Andrei Viktorovich
AU - Ivchenko, Pavel Vasil'evich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 467-469
IS - 5
VL - 28
ER -
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@article{2018_Nifant'ev,
author = {Ilya Eduardovich Nifant'ev and Alexander Andreevich Vinogradov and Alexey Andreevich Vinogradov and Andrei Viktorovich Churakov and Pavel Vasil'evich Ivchenko},
title = {Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.004},
number = {5},
pages = {467--469},
doi = {10.1016/j.mencom.2018.09.004}
}
MLA
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Nifant'ev, Ilya Eduardovich, et al. “Synthesis of zirconium(III) complex by reduction of O[SiMe2(η5-C5H4)]2ZrCl2 and its selectivity in catalytic dimerization of hex-1-ene.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 467-469. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.004.

Abstract

ansa-Complex O[SiMe2(η5-C5H4)]2ZrCl2 upon reduction with LiAlH4 in contrast to zirconocene dichloride forms a dia-magnetic ZrIII complex with the dimeric molecular structure proved by X-ray analysis. This complex after activation by MeAlO initiates oligomerization of α-olefins.

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