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Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond

Liana Arthur Hayriyan 1
Liana Arthur Hayriyan
, 
Anna F Mkrtchyan 1
Anna F Mkrtchyan
, 
Margarita Alekseevna Moskalenko 2
Margarita Alekseevna Moskalenko
,  , 
Zalina Taymurazovna Gugkaeva 2
Zalina Taymurazovna Gugkaeva
, 
Mikhail Mikhailovich Ilyin 2
Mikhail Mikhailovich Ilyin
, 
Kirill Konstantinovich Babievsky 2
Kirill Konstantinovich Babievsky
, 
Pavel Vladimirovich Dorovatovskii 3
Pavel Vladimirovich Dorovatovskii
, 
Victor Nikolaevich Khrustalev 3, 4
Victor Nikolaevich Khrustalev
, 
Aleksandr Sergeevich Peregudov 2
Aleksandr Sergeevich Peregudov
, 
Yurii Nikolaevich Belokon 2
Yurii Nikolaevich Belokon
10.1016/j.mencom.2018.09.003
Published 2018-09-07
Communication , Volume 28, Issue 5, 464-466
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Hayriyan L. A. et al. Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 464-466.
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Hayriyan L. A., Mkrtchyan A. F., Moskalenko M. A., Maleev V. I., Gugkaeva Z. T., Ilyin M. M., Babievsky K. K., Dorovatovskii P. V., Khrustalev V. N., Peregudov A. S., Belokon Y. N. Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond // Mendeleev Communications. 2018. Vol. 28. No. 5. pp. 464-466.
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TY - JOUR
DO - 10.1016/j.mencom.2018.09.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.003
TI - Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond
T2 - Mendeleev Communications
AU - Hayriyan, Liana Arthur
AU - Mkrtchyan, Anna F
AU - Moskalenko, Margarita Alekseevna
AU - Maleev, Victor Ivanovich
AU - Gugkaeva, Zalina Taymurazovna
AU - Ilyin, Mikhail Mikhailovich
AU - Babievsky, Kirill Konstantinovich
AU - Dorovatovskii, Pavel Vladimirovich
AU - Khrustalev, Victor Nikolaevich
AU - Peregudov, Aleksandr Sergeevich
AU - Belokon, Yurii Nikolaevich
PY - 2018
DA - 2018/09/07
PB - Mendeleev Communications
SP - 464-466
IS - 5
VL - 28
ER -
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@article{2018_Hayriyan,
author = {Liana Arthur Hayriyan and Anna F Mkrtchyan and Margarita Alekseevna Moskalenko and Victor Ivanovich Maleev and Zalina Taymurazovna Gugkaeva and Mikhail Mikhailovich Ilyin and Kirill Konstantinovich Babievsky and Pavel Vladimirovich Dorovatovskii and Victor Nikolaevich Khrustalev and Aleksandr Sergeevich Peregudov and Yurii Nikolaevich Belokon},
title = {Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.003},
number = {5},
pages = {464--466},
doi = {10.1016/j.mencom.2018.09.003}
}
MLA
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MLA Copy
Hayriyan, Liana Arthur, et al. “Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond.” Mendeleev Communications, vol. 28, no. 5, Sep. 2018, pp. 464-466. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.09.003.

Abstract

A representative within a new class of chiral enol NiII complexes derived from a Schiff base of aminoacetone and (S)-2-N-(N-benzylprolinoylamino)benzophenone was prepared, and its performance in nucleophilic addition was estimated. The complex was inert towards aldehydes and activated C=C bonds but reacted with carboxylic anhydrides and di-tert-butyl acetylenedicarboxylate. An unusual Michael addition intermediate stabilized by the Ni–C bond was discovered in the latter reaction.

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