Home / Publications / Synthesis of halodifluoromethyl-substituted phosphines

Synthesis of halodifluoromethyl-substituted phosphines

Roman O Iakovenko 1
Roman O Iakovenko
, 
10.1016/j.mencom.2018.07.018
Published 2018-06-29
Communication , Volume 28, Issue 4, 396-397
3
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Iakovenko R. O., Dilman A. D. Synthesis of halodifluoromethyl-substituted phosphines // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 396-397.
GOST all authors (up to 50) Copy
Iakovenko R. O., Dilman A. D. Synthesis of halodifluoromethyl-substituted phosphines // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 396-397.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2018.07.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.018
TI - Synthesis of halodifluoromethyl-substituted phosphines
T2 - Mendeleev Communications
AU - Iakovenko, Roman O
AU - Dilman, Alexander Davidovich
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 396-397
IS - 4
VL - 28
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Iakovenko,
author = {Roman O Iakovenko and Alexander Davidovich Dilman},
title = {Synthesis of halodifluoromethyl-substituted phosphines},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.018},
number = {4},
pages = {396--397},
doi = {10.1016/j.mencom.2018.07.018}
}
MLA
Cite this
MLA Copy
Iakovenko, Roman O., and Alexander Davidovich Dilman. “Synthesis of halodifluoromethyl-substituted phosphines.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 396-397. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.018.

Abstract

Three phosphines bearing halodifluoromethyl group were obtained starting from chlorodiphenylphosphine. Silicon reagents Me3SiCF2X (X=Cl, Br) were used to install chloroor bromodifluoromethyl group to the phosphorus atom. Iododifluoromethyl-substituted phosphine was prepared by bromine/iodine exchange.

References

1.
Monofluoro- and difluoro-methylenebisphosphonic acids: isopolar analogues of pyrophosphoric acid
Blackburn G.M., England D.A., Kolkmann F.
Journal of the Chemical Society Chemical Communications, 1981
2.
The synthesis and metal binding characteristics of novel, isopolar phosphonate analogues of nucleotides
Blackburn G.M., Kent D.E., Kolkmann F.
Journal of the Chemical Society Perkin Transactions 1, 1984
5.
Difluoromethylenephosphonates: synthesis and transformations
Chunikhin K.S., Kadyrov A.A., Pasternak P.V., Chkanikov N.D.
Russian Chemical Reviews, 2010
6.
10.1016/j.mencom.2018.07.018_sbref0015b
Beier
Chem. Listy, 2014
7.
The synthesis of tris(perfluoroalkyl)phosphines
Murphy-Jolly M.B., Lewis L.C., Caffyn A.J.
Chemical Communications, 2005
8.
Syntheses and characterization of bis(trifluoromethyl)phosphino naphthalenes and acenaphthenes
Wawrzyniak P., Slawin A.M., Woollins J.D., Kilian P.
Dalton Transactions, 2010
11.
A generic route to fluoroalkyl-containing phosphanes
Brisdon A.K., Herbert C.J.
Chemical Communications, 2009
16.
Ananikov V.P., Eremin D.B., Yakukhnov S.A., Dilman A.D., Levin V.V., Egorov M.P., Karlov S.S., Kustov L.M., Tarasov A.L., Greish A.A., Shesterkina A.A., Sakharov A.M., Nysenko Z.N., Sheremetev A.B., Stakheev A.Y., et. al.
Mendeleev Communications, 2017
17.
Nucleophilic Bromodifluoromethylation of Iminium Ions
Tsymbal A.V., Kosobokov M.D., Levin V.V., Struchkova M.I., Dilman A.D.
Journal of Organic Chemistry, 2014
20.
Nucleophilic Bromo- and Iododifluoromethylation of Aldehydes
Kosobokov M.D., Levin V.V., Struchkova M.I., Dilman A.D.
Organic Letters, 2014
21.
Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
Kosobokov M.D., Dilman A.D., Levin V.V., Struchkova M.I.
Journal of Organic Chemistry, 2012