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Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates

, 
Alexander Fedorovich Smol'yakov 1
Alexander Fedorovich Smol'yakov
, 
Kristina Fedorovna Baranova 1
Kristina Fedorovna Baranova
,  , 
10.1016/j.mencom.2018.07.015
Published 2018-06-29
Communication , Volume 28, Issue 4, 387-389
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Titov A. A. et al. Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 387-389.
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Titov A. A., Smol'yakov A. F., Baranova K. F., Filippov O. A., Shubina E. S. Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 387-389.
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TY - JOUR
DO - 10.1016/j.mencom.2018.07.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.015
TI - Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates
T2 - Mendeleev Communications
AU - Titov, Aleksei Aleksandrovich
AU - Smol'yakov, Alexander Fedorovich
AU - Baranova, Kristina Fedorovna
AU - Filippov, Oleg Andreevich
AU - Shubina, Elena Solomonovna
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 387-389
IS - 4
VL - 28
ER -
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@article{2018_Titov,
author = {Aleksei Aleksandrovich Titov and Alexander Fedorovich Smol'yakov and Kristina Fedorovna Baranova and Oleg Andreevich Filippov and Elena Solomonovna Shubina},
title = {Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.015},
number = {4},
pages = {387--389},
doi = {10.1016/j.mencom.2018.07.015}
}
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Titov, Aleksei Aleksandrovich, et al. “Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 387-389. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.015.

Abstract

Reaction of a trinuclear silver pyrazolate {[3,5-(CF3)2Pz]Ag}3 complex with tricyclohexylphosphine at different reagent ratios leads to the formation of heteroleptic dinuclear or tetranuclear complexes. According to the single crystal X-ray analysis of the dinuclear complex, hexane molecules are incorporated into the cavities formed as the result of supramolecular packing. Coordination of a phosphine ligand makes dinuclear silver pyrazolate to exhibit blue emission at room temperature.

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