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Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies

Ivan Sergeevich Zhidkov 1
Ivan Sergeevich Zhidkov
, 
Azat Fatkhulovich Akbulatov 2
Azat Fatkhulovich Akbulatov
, 
Andrey Igorevich Kukharenko 1
Andrey Igorevich Kukharenko
,  , 
Keith J Stevenson 3
Keith J Stevenson
, 
Pavel Anatol'evich Troshin 2, 3
Pavel Anatol'evich Troshin
, 
Ernst Z Kurmaev 1, 4
Ernst Z Kurmaev
10.1016/j.mencom.2018.07.013
Published 2018-06-29
Communication , Volume 28, Issue 4, 381-383
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Zhidkov I. S. et al. Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 381-383.
GOST all authors (up to 50) Copy
Zhidkov I. S., Akbulatov A. F., Kukharenko A. I., Cholakh S. O., Stevenson K. J., Troshin P. A., Kurmaev E. Z. Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 381-383.
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TY - JOUR
DO - 10.1016/j.mencom.2018.07.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.013
TI - Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies
T2 - Mendeleev Communications
AU - Zhidkov, Ivan Sergeevich
AU - Akbulatov, Azat Fatkhulovich
AU - Kukharenko, Andrey Igorevich
AU - Cholakh, Seif Osmanovich
AU - Stevenson, Keith J
AU - Troshin, Pavel Anatol'evich
AU - Kurmaev, Ernst Z
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 381-383
IS - 4
VL - 28
ER -
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@article{2018_Zhidkov,
author = {Ivan Sergeevich Zhidkov and Azat Fatkhulovich Akbulatov and Andrey Igorevich Kukharenko and Seif Osmanovich Cholakh and Keith J Stevenson and Pavel Anatol'evich Troshin and Ernst Z Kurmaev},
title = {Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.013},
number = {4},
pages = {381--383},
doi = {10.1016/j.mencom.2018.07.013}
}
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Zhidkov, Ivan Sergeevich, et al. “Influence of halide mixing on thermal and photochemical stability of hybrid perovskites: XPS studies.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 381-383. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.013.

Abstract

The effect of I–/Cl–and I–/Br–mixing on the thermal and photochemical degradation of organometallic perovskite MeNH3PbI3 (MAPbI3) was studied by X-ray photoelectron spectroscopy, which revealed the opportunity to essentially increase the photo and thermal stabilities of the material depending on the level and position of halide-mixing. The largest positive effect was observed for the small concentration of chloride substituent (MAPbI2.7Cl0.3), while the full halide substitution (MAPbBr3) had a negative effect on the stability of hybrid perovskite.

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