Home / Publications / Boiling-induced changes in the mechanism of diglyme radiolysis

Boiling-induced changes in the mechanism of diglyme radiolysis

Alexandr Vladimirovich Ponomarev 1
Alexandr Vladimirovich Ponomarev
, 
Eugenia Mikhailovna Kholodkova 1
Eugenia Mikhailovna Kholodkova
10.1016/j.mencom.2018.07.011
Published 2018-06-29
Communication , Volume 28, Issue 4, 375-377
9
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Ponomarev A. V., Kholodkova E. M. Boiling-induced changes in the mechanism of diglyme radiolysis // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 375-377.
GOST all authors (up to 50) Copy
Ponomarev A. V., Kholodkova E. M. Boiling-induced changes in the mechanism of diglyme radiolysis // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 375-377.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2018.07.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.011
TI - Boiling-induced changes in the mechanism of diglyme radiolysis
T2 - Mendeleev Communications
AU - Ponomarev, Alexandr Vladimirovich
AU - Kholodkova, Eugenia Mikhailovna
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 375-377
IS - 4
VL - 28
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Ponomarev,
author = {Alexandr Vladimirovich Ponomarev and Eugenia Mikhailovna Kholodkova},
title = {Boiling-induced changes in the mechanism of diglyme radiolysis},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.011},
number = {4},
pages = {375--377},
doi = {10.1016/j.mencom.2018.07.011}
}
MLA
Cite this
MLA Copy
Ponomarev, Alexandr Vladimirovich, and Eugenia Mikhailovna Kholodkova. “Boiling-induced changes in the mechanism of diglyme radiolysis.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 375-377. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.011.

Abstract

Boiling intensifies the radiolytic conversion of diglyme since it stimulates the cleavage of the C–O bonds in the excited molecules and the primary radical cations, enhances the radical exchange reactions, and weakens the diglyme regeneration reactions.

References

1.
R. J. Woods and A. K. Pikaev, Applied Radiation Chemistry: Radiation Processing, Wiley-Interscience, New York, 1994.
2.
L. V. Grekhov and V. A. Markov, Transport na Al’ternativnom Toplive, 2010, no. 3, 62 (in Russian).
3.
Kinetic modeling of the destruction of methyl tert-butyl ether (MTBE)
Cooper W.J., Mezyk S.P., O’Shea K.E., Kim D.K., Hardison D.R.
Radiation Physics and Chemistry, 2003
4.
Radiolysis of Liquid Di-n-propyl Ether: Alcohol Formation and Solvated Electrons
Vermeer R.A., Freeman G.R.
Canadian Journal of Chemistry, 1974
5.
Gamma radiolysis of methyl t-butyl ether: a study of hydroxyl radical mediated reaction pathways
Wu T., Cruz V., Mezyk S., Cooper W.J., O’Shea K.E.
Radiation Physics and Chemistry, 2002
7.
Gamma-radiolysis of some crown ethers and their analogues. Electron spin resonance specra of free radicals
Kuruc J., Šeršeň F.
Journal of Radioanalytical and Nuclear Chemistry, 1990
9.
R. M. Silverstein, G.C. Bassler and T. C. Morrill, Spectrometric Identification of Organic Compounds, Wiley, New York, 1974.
10.
G. Cserép, I. György, M. Roder and L. Wojnárovits, Radiation Chemistry of Hydrocarbons, ed. G. Földiák, Akadémiai Kiadó, Budapest, 1981.