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New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions

Mikhail Mikhailovich Shmakov 1, 2
Mikhail Mikhailovich Shmakov
, 
Sergey Alexandrovich Prikhod’ko 1, 2
Sergey Alexandrovich Prikhod’ko
, 
Vadim Victorovich Bardin 2, 3
Vadim Victorovich Bardin
, 
Nicolay Yur'evich Adonin 1, 2
Nicolay Yur'evich Adonin
10.1016/j.mencom.2018.07.009
Published 2018-06-29
Communication , Volume 28, Issue 4, 369-371
7
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Shmakov M. M. et al. New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 369-371.
GOST all authors (up to 50) Copy
Shmakov M. M., Prikhod’ko S. A., Bardin V. V., Adonin N. Y. New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 369-371.
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TY - JOUR
DO - 10.1016/j.mencom.2018.07.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.009
TI - New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions
T2 - Mendeleev Communications
AU - Shmakov, Mikhail Mikhailovich
AU - Prikhod’ko, Sergey Alexandrovich
AU - Bardin, Vadim Victorovich
AU - Adonin, Nicolay Yur'evich
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 369-371
IS - 4
VL - 28
ER -
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@article{2018_Shmakov,
author = {Mikhail Mikhailovich Shmakov and Sergey Alexandrovich Prikhod’ko and Vadim Victorovich Bardin and Nicolay Yur'evich Adonin},
title = {New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.009},
number = {4},
pages = {369--371},
doi = {10.1016/j.mencom.2018.07.009}
}
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Shmakov, Mikhail Mikhailovich, et al. “New approach to the generation of aryldifluoroboranes–prospective acid catalysts of organic reactions.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 369-371. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.009.

Abstract

A new approach for preparation of aromatic and fluoroaromatic difluoroboranes via the interaction between corresponding aryltrifluoroborates and ionic liquids containing tetrachloroaluminate-anion and aluminum chloride has been developed. Catalytic properties of obtained aryldifluoroboranes have been investigated in model reactions of phenols alkylation. The dependence of catalytic properties on both the nature of solvent used and the type of substituents in the aromatic ring of difluoroborane has been established.

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