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CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity

Sofya Sergeevna Kuvshinova 1
Sofya Sergeevna Kuvshinova
, 
Alexander Fedorovich Smol'yakov 1, 2
Alexander Fedorovich Smol'yakov
, 
Daria Vladimirovna Vorobyeva 1
Daria Vladimirovna Vorobyeva
, 
Sergey Nikolaevich Osipov 1
Sergey Nikolaevich Osipov
, 
Dmitry Alexandrovich Loginov 1
Dmitry Alexandrovich Loginov
10.1016/j.mencom.2018.07.005
Published 2018-06-29
Communication , Volume 28, Issue 4, 359-361
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Kuvshinova S. S. et al. CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 359-361.
GOST all authors (up to 50) Copy
Kuvshinova S. S., Smol'yakov A. F., Vorobyeva D. V., Osipov S. N., Loginov D. A. CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity // Mendeleev Communications. 2018. Vol. 28. No. 4. pp. 359-361.
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TY - JOUR
DO - 10.1016/j.mencom.2018.07.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.005
TI - CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity
T2 - Mendeleev Communications
AU - Kuvshinova, Sofya Sergeevna
AU - Smol'yakov, Alexander Fedorovich
AU - Vorobyeva, Daria Vladimirovna
AU - Osipov, Sergey Nikolaevich
AU - Loginov, Dmitry Alexandrovich
PY - 2018
DA - 2018/06/29
PB - Mendeleev Communications
SP - 359-361
IS - 4
VL - 28
ER -
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@article{2018_Kuvshinova,
author = {Sofya Sergeevna Kuvshinova and Alexander Fedorovich Smol'yakov and Daria Vladimirovna Vorobyeva and Sergey Nikolaevich Osipov and Dmitry Alexandrovich Loginov},
title = {CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.005},
number = {4},
pages = {359--361},
doi = {10.1016/j.mencom.2018.07.005}
}
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Kuvshinova, Sofya Sergeevna, et al. “CF3-Carbenoid functionalization of N-(pyrimidin-2-yl)indole catalyzed by cobalt complexes: Ligand control of selectivity.” Mendeleev Communications, vol. 28, no. 4, Jun. 2018, pp. 359-361. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.07.005.

Abstract

The carbonyl cobalt complex Cp*Co(CO)I2 catalyzes carbenoid Co alkylation of N-(pyrimidin-2-yl)indole with methyl 3,3,3-trifluoro-2-diazopropionate regioselectively giving 2-substituted indole, while the N,N’-ligated cations [CpCo(L)I]+ (L=bipy, phen) provide 3-substitution exclusively. The structure of [CpCo(phen)I]PF6 was investigated by X-ray diffraction.

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