Abstract
It has been found that leaching of AmIII from the surface after the sorption is characterized by slow kinetics; over 10 days are required to reach a dynamic equilibrium in the system. The leaching process is accompanied by the formation of Am-containing phosphate phase on the sorbent surface. Annealing the sample at 400°C for 5h after sorption results in incorporation of the sorbed cation into the sorbent structure, which allows subsequent leaching to be reduced considerably.
References
1.
Myasoedov B.F., Kalmykov S.N.
Mendeleev Communications,
2015
2.
10.1016/j.mencom.2018.05.025_bib0010
Yudintsev
Structural Chemistry of Inorganic Actinide Compounds,
2007
3.
10.1016/j.mencom.2018.05.025_bib0015
Lutze
Radioactive Waste Forms for the Future,
1988
4.
Stefanovsky S.V., Yudintsev S.V., Vinokurov S.E., Myasoedov B.F.
Geochemistry International,
2016
5.
N.P. Laverov, V.I. Velichkin, B.I. Omel’yanenko, S.V. Yudintsev, V.A. Petrov, A. V. Bychkov, Izolyatsiya otrabotavshikh yadernykh materialov: geologo-geokhimicheskie osnovy (Insulation of Spent Nuclear Materials: Gelogical and Geochemical Bases), IFZ RAN, Moscow, 2008 (in Russian).
6.
Sorption of Am-III onto orthophosphates of the rare-earth elements with different crystal structures
Gracheva N.N., Romanchuk A.Y., Bryukhanova K.I., Gavrichev K.S., Kalmykov S.N.
Mendeleev Communications,
2017
7.
Dacheux N., Clavier N., Podor R.
American Mineralogist,
2013
8.
Chernyshov A.A., Veligzhanin A.A., Zubavichus Y.V.
Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment,
2009
9.
Poitrasson F., Oelkers E., Schott J., Montel J.
Geochimica et Cosmochimica Acta,
2004
10.
Cetiner Z.S., Wood S.A., Gammons C.H.
Chemical Geology,
2005
11.
Clavier N., Dacheux N., Martinez P., Brandel V., Podor R., Le Coustumer P.
Journal of Nuclear Materials,
2004
12.
Du Fou de Kerdaniel E., Clavier N., Dacheux N., Terra O., Podor R.
Journal of Nuclear Materials,
2007
13.
Thomas A.C., Dacheux N., Le Coustumer P., Brandel V., Genet M.
Journal of Nuclear Materials,
2000
14.
Dacheux N., Clavier N., Ritt J.
Journal of Nuclear Materials,
2006
15.
Terra O., Clavier N., Dacheux N., Podor R.
New Journal of Chemistry,
2003