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Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom

Vladimir Ilyich Smirnov 1
Vladimir Ilyich Smirnov
, 
Eleonora A Zelbst 2
Eleonora A Zelbst
, 
Galina Alekseevna Kuznetsova 1
Galina Alekseevna Kuznetsova
, 
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
10.1016/j.mencom.2018.05.016
Published 2018-04-27
Communication , Volume 28, Issue 3, 278-280
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Smirnov V. I. et al. Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 278-280.
GOST all authors (up to 50) Copy
Smirnov V. I., Zelbst E. A., Kuznetsova G. A., Sterkhova I. V. Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 278-280.
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TY - JOUR
DO - 10.1016/j.mencom.2018.05.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.016
TI - Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom
T2 - Mendeleev Communications
AU - Smirnov, Vladimir Ilyich
AU - Zelbst, Eleonora A
AU - Kuznetsova, Galina Alekseevna
AU - Sterkhova, Irina Vladimirovna
PY - 2018
DA - 2018/04/27
PB - Mendeleev Communications
SP - 278-280
IS - 3
VL - 28
ER -
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@article{2018_Smirnov,
author = {Vladimir Ilyich Smirnov and Eleonora A Zelbst and Galina Alekseevna Kuznetsova and Irina Vladimirovna Sterkhova},
title = {Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.016},
number = {3},
pages = {278--280},
doi = {10.1016/j.mencom.2018.05.016}
}
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Smirnov, Vladimir Ilyich, et al. “Crystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom.” Mendeleev Communications, vol. 28, no. 3, Apr. 2018, pp. 278-280. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.016.

Abstract

Crystal and molecular structures of two silatranes, 1-iodomethyl-3-methyl- and 1-iodomethyl-3,7,10-trimethyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecanes, were determined by X-ray analysis. Comparison of their structural and geometrical characteristics with those of other silatranes shows that the presence of methyl substituents β-positioned to nitrogen atoms increases the length of the dative Si←N bond, whereas the introduction of iodine into the axial position of the silatrane slightly decreases the length of the Si←N bond.

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