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Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range

Evgeniya Aleksandrovna Safonova 1
Evgeniya Aleksandrovna Safonova
,  , 
Marina Aleksandrovna Polovkova 1
Marina Aleksandrovna Polovkova
, 
Marina Vladimirovna Volostnykh 1
Marina Vladimirovna Volostnykh
, 
Aslan Yusupovich Tsivadze 1, 2
Aslan Yusupovich Tsivadze
, 
Yulia Germanovna Gorbunova 1, 2
Yulia Germanovna Gorbunova
10.1016/j.mencom.2018.05.015
Published 2018-04-27
Communication , Volume 28, Issue 3, 275-277
17
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Safonova E. A. et al. Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 275-277.
GOST all authors (up to 50) Copy
Safonova E. A., Meshkov I. N., Polovkova M. A., Volostnykh M. V., Tsivadze A. Y., Gorbunova Y. G. Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 275-277.
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TY - JOUR
DO - 10.1016/j.mencom.2018.05.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.015
TI - Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range
T2 - Mendeleev Communications
AU - Safonova, Evgeniya Aleksandrovna
AU - Meshkov, Ivan Nikolaevich
AU - Polovkova, Marina Aleksandrovna
AU - Volostnykh, Marina Vladimirovna
AU - Tsivadze, Aslan Yusupovich
AU - Gorbunova, Yulia Germanovna
PY - 2018
DA - 2018/04/27
PB - Mendeleev Communications
SP - 275-277
IS - 3
VL - 28
ER -
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@article{2018_Safonova,
author = {Evgeniya Aleksandrovna Safonova and Ivan Nikolaevich Meshkov and Marina Aleksandrovna Polovkova and Marina Vladimirovna Volostnykh and Aslan Yusupovich Tsivadze and Yulia Germanovna Gorbunova},
title = {Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.015},
number = {3},
pages = {275--277},
doi = {10.1016/j.mencom.2018.05.015}
}
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Safonova, Evgeniya Aleksandrovna, et al. “Photophysical and photochemical properties of non-peripheral butoxy-substituted phthalocyanines with absorption in NIR range.” Mendeleev Communications, vol. 28, no. 3, Apr. 2018, pp. 275-277. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.015.

Abstract

The optical properties of non-peripheral octabutoxyphthalocyanine (PcH2) and the corresponding complexes PcM (M =MgII, ZnII, GaIII, InIII) in DMSO solutions were examined. Singlet oxygen generation quantum yields increase in the sequence PcH2 < PcMg < PcInCl < PcGaCl < PcZn and vary from 4 up to 36%; protonation of PcM quenches both fluorescence and singlet oxygen generation. The photocatalytic activity of PcGaCl in the photooxidation of 1,5-dihydroxynaphthalene was revealed.

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