Abstract
Rhodium-catalysed hydroformylation of styrene and aliphatic olefins under biphasic conditions in the presence of watersoluble 1,4,7-triaza-9-phosphatricyclo[5.3.2.14,9]tridecane (CAP) chemoselectively affords aldehydes. Multiple catalyst reuse without loss in performance is demonstrated.
References
1.
Beller M., Cornils B., Frohning C.D., Kohlpaintner C.W.
Journal of Molecular Catalysis A Chemical,
1995
2.
Frey G.D.
Journal of Organometallic Chemistry,
2014
3.
Bohnen H., Cornils B.
Advances in Catalysis,
2002
4.
Rhodium Catalyzed Hydroformylation, eds. P. W. N. M. van Leeuwen and C. Claver, Kluwer Academic Publishers, Dordrecht, 2002.
5.
Klosin J., Landis C.R.
Accounts of Chemical Research,
2007
6.
7.
Trzeciak A.M., Ziółkowski J.J.
Coordination Chemistry Reviews,
1999
8.
10.1016/j.mencom.2018.05.011_bib0040
Kuntz
Chemtech,
1987
9.
B. Cornils and E. G. Kuntz, in Aqueous-Phase Organometallic Catalysis, eds. B. Cornils and W. A. Herrmann, Wiley–VCH, Weinheim, 1998, pp. 271-339.
10.
Kohlpaintner C.W., Fischer R.W., Cornils B.
Applied Catalysis A: General,
2001
11.
Willner I., Maidan R.
Journal of the Chemical Society Chemical Communications,
1988
12.
Bahrmann H., Bergrath K., Kleiner H., Lappe P., Naumann C., Peters D., Regnat D.
Journal of Organometallic Chemistry,
1996
13.
Bischoff S., Kant M.
Industrial & Engineering Chemistry Research,
2000
14.
Bischoff S., Kant M.
Catalysis Today,
2001
15.
Suárez T., Fontal B., León G., Reyes M., Bellandi F., Contreras R.R., Cancines P.
Transition Metal Chemistry,
2006
16.
Hamerla T., Rost A., Kasaka Y., Schomäcker R.
ChemCatChem,
2013
17.
Mieczyńska E., Trzeciak A.M., Ziółkowski J.J.
Journal of Molecular Catalysis A Chemical,
1999
18.
Son S.U., Han J.W., Chung Y.K.
Journal of Molecular Catalysis A Chemical,
1998
19.
Borrmann T., Roesky H.W., Ritter U.
Journal of Molecular Catalysis A Chemical,
2000
20.
Phillips A.D., Gonsalvi L., Romerosa A., Vizza F., Peruzzini M.
Coordination Chemistry Reviews,
2004
21.
Bravo J., Bolaño S., Gonsalvi L., Peruzzini M.
Coordination Chemistry Reviews,
2010
22.
Pruchnik F.P., Smoleñski P., Gałdecka E., Gałdecki Z.
New Journal of Chemistry,
1998
23.
Pruchnik F.P., Smoleński P., Wajda-Hermanowicz K.
Journal of Organometallic Chemistry,
1998
24.
Phillips A.D., Bolaño S., Bosquain S.S., Daran J., Malacea R., Peruzzini M., Poli R., Gonsalvi L.
Organometallics,
2006
25.
Britvin S.N., Lotnyk A.
Journal of the American Chemical Society,
2015
26.
Britvin S.N., Rumyantsev A.M., Zobnina A.E., Padkina M.V.
Chemistry - A European Journal,
2016
27.
MacDougall J.K., Cole-Hamilton D.J.
Journal of the Chemical Society Chemical Communications,
1990
28.
MacDougall J.K., Simpson M.C., Green M.J., Cole-Hamilton D.J.
Journal of the Chemical Society Dalton Transactions,
1996
29.
Dougherty T.P., Grubbs W.T., Heilweil E.J.
The Journal of Physical Chemistry,
1994
30.
Brink A., Roodt A., Steyl G., Visser H.G.
Dalton Transactions,
2010
31.
Rampf F.A., Herrmann W.A.
Journal of Organometallic Chemistry,
2000
32.
Giacomini D., Galletti P., Quintavalla A., Gucciardo G., Paradisi F.
Chemical Communications,
2007