Abstract
Highly effective embodiment of Sandmeyer reaction has been revealed for Cu-based catalysts incorporating ionic liquid on Silochrom support. The most active catalyst (TOF = = 4000–8000 h–1) contains comparable amounts of cuprous and cupric chloride anions. The reported method allows one to carry out the reaction for anilines in the one-pot mode.
References
1.
2.
Kochi J.K.
Journal of the American Chemical Society,
1957
3.
4.
Zollinger H.
Accounts of Chemical Research,
1973
5.
Galli C.
Chemical Reviews,
1988
6.
Dai J., Fang C., Xiao B., Yi J., Xu J., Liu Z., Lu X., Liu L., Fu Y.
Journal of the American Chemical Society,
2013
7.
Hubbard A., Okazaki T., Laali K.K.
Journal of Organic Chemistry,
2007
8.
Matheis C., Wagner V., Goossen L.J.
Chemistry - A European Journal,
2015
9.
Danoun G., Bayarmagnai B., Grünberg M.F., Gooßen L.J.
Angewandte Chemie - International Edition,
2013
10.
Nikolaienko P., Rueping M.
Chemistry - A European Journal,
2016
11.
Sigeev A.S., Beletskaya I.P., Petrovskii P.V., Peregudov A.S.
Russian Journal of Organic Chemistry,
2012
12.
Beletskaya I., Sigeev A., Peregudov A., Petrovskii P.
Synthesis,
2007
13.
Yin D., He Y., Perera M.A., Hong S.S., Marhefka C., Stourman N., Kirkovsky L., Miller D.D., Dalton J.T.
Molecular Pharmacology,
2003
14.
Goldberg J., Jin Q., Ambroise Y., Satoh S., Desharnais J., Capps K., Boger D.L.
Journal of the American Chemical Society,
2001
15.
Supported Ionic Liquids. Fundamental and Applications, eds. R. Fehrmann, A. Riisager and M. Haumann, Wiley-VCH, Weinheim, 2014.
16.
Zelikman V.M., Tarkhanova I.G., Khomyakova E.V.
Kinetics and Catalysis,
2012
17.
Zelikman V.M., Tarkhanova I.G., Buryak A.K.
Journal of Molecular Catalysis A Chemical,
2015
18.
Huang C., Chen B., Zhang J., Liu Z., Li Y.
Energy & Fuels,
2004
19.
Beletskaya I.P., Sigeev A.S., Peregudov A.S., Petrovskii P.V.
Journal of Organometallic Chemistry,
2004
20.
Beletskaya I.P., Cheprakov A.V.
Chemical Reviews,
2000