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Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures

Leonid Anatol'evich Shundrin 1, 2
Leonid Anatol'evich Shundrin
, 
Irina Gennad'evna Irtegova 1
Irina Gennad'evna Irtegova
, 
Nadezhda Vasilievna Vasilieva 1
Nadezhda Vasilievna Vasilieva
, 
Vladimir Alekseevich Loskutov 1
Vladimir Alekseevich Loskutov
10.1016/j.mencom.2018.05.009
Published 2018-04-27
Communication , Volume 28, Issue 3, 257-260
2
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Shundrin L. A. et al. Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 257-260.
GOST all authors (up to 50) Copy
Shundrin L. A., Irtegova I. G., Vasilieva N. V., Loskutov V. A. Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 257-260.
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TY - JOUR
DO - 10.1016/j.mencom.2018.05.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.009
TI - Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures
T2 - Mendeleev Communications
AU - Shundrin, Leonid Anatol'evich
AU - Irtegova, Irina Gennad'evna
AU - Vasilieva, Nadezhda Vasilievna
AU - Loskutov, Vladimir Alekseevich
PY - 2018
DA - 2018/04/27
PB - Mendeleev Communications
SP - 257-260
IS - 3
VL - 28
ER -
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@article{2018_Shundrin,
author = {Leonid Anatol'evich Shundrin and Irina Gennad'evna Irtegova and Nadezhda Vasilievna Vasilieva and Vladimir Alekseevich Loskutov},
title = {Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.009},
number = {3},
pages = {257--260},
doi = {10.1016/j.mencom.2018.05.009}
}
MLA
Cite this
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Shundrin, Leonid Anatol'evich, et al. “Electrochemical reduction, radical anions and solvation energies of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its N-piperidyl derivatives in DMF and DMF–water mixtures.” Mendeleev Communications, vol. 28, no. 3, Apr. 2018, pp. 257-260. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.05.009.

Abstract

The electrochemical reduction of 1,2,3,4-tetrafluoro-9,10-anthraquinone and its 2-(N-piperidyl) derivative in DMF and DMF–H2O mixtures represents an EE-process, whereas that for 1-(N-piperidyl) and 1,4-di(N-piperidyl) derivatives occurs as an EEC-process. Based on the linear dependences of the first reversible one-electron reductive half-wave potentials of these compounds on the water content of DMF–H2O mixtures, the corresponding changes in the free energies of solvation under electron transfer have been calculated. Radical anions of the above compounds were obtained in DMF and characterized by EPR spectroscopy and DFT calculations at the (U)B3LYP/6-31+G* level of theory.

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