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Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes

Chunyang Zheng 1, 2
Chunyang Zheng
, 
Xuecheng Hu 2
Xuecheng Hu
, 
Qin Tao 1
Qin Tao
1 Institute for Advanced Materials, Hubei Normal University, Huangshi, P.R. China
2 Department of Chemistry, The School of Art and Science of Hubei Normal University, Huangshi, P.R. China
10.1016/j.mencom.2018.03.034
Published 2018-03-01
Communication , Volume 28, Issue 2, 208-210
7
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Zheng C., Hu X., Tao Q. Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes // Mendeleev Communications. 2018. Vol. 28. No. 2. pp. 208-210.
GOST all authors (up to 50) Copy
Zheng C., Hu X., Tao Q. Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes // Mendeleev Communications. 2018. Vol. 28. No. 2. pp. 208-210.
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TY - JOUR
DO - 10.1016/j.mencom.2018.03.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.034
TI - Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes
T2 - Mendeleev Communications
AU - Zheng, Chunyang
AU - Hu, Xuecheng
AU - Tao, Qin
PY - 2018
DA - 2018/03/01
PB - Mendeleev Communications
SP - 208-210
IS - 2
VL - 28
ER -
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@article{2018_Zheng,
author = {Chunyang Zheng and Xuecheng Hu and Qin Tao},
title = {Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.034},
number = {2},
pages = {208--210},
doi = {10.1016/j.mencom.2018.03.034}
}
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Zheng, Chunyang, et al. “Synthesis, structures and magnetic properties of two iron(ii) tris(pyridyl)phosphine sulfide complexes.” Mendeleev Communications, vol. 28, no. 2, Mar. 2018, pp. 208-210. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.034.

Abstract

Two iron(ii) mononuclear metal complexes with tris(pyridyl)-phosphine sulfides and Fe(ClO4)2·6H2O have been synthesized and characterized. Detailed structural analyses and magnetic susceptibility measurements confirm no spin transition from low-spin to the high-spin state between 2 and 300 K in these complexes.

References

1.
Pyridylphosphines
Newkome G.R.
Chemical Reviews, 1993
2.
Chemistry of 2-(diphenylphosphino)pyridine
Zhang Z., Cheng H.
Coordination Chemistry Reviews, 1996
3.
Phosphine-pyridyl and related ligands in synthesis and catalysis
Espinet P., Soulantica K.
Coordination Chemistry Reviews, 1999
4.
Tris(2-pyridyl) tripod ligands
Szczepura L.F., Witham L.M., Takeuchi K.J.
Coordination Chemistry Reviews, 1998
6.
Artem’ev A.V., Gusarova N.K., Malysheva S.F., Kazheva O.N., Alexandrov G.G., Dyachenko O.A., Trofimov B.A.
Mendeleev Communications, 2012
7.
Artem’ev A.V., Gusarova N.K., Sutyrina A.O., Gatilov Y.V., Trofimov B.A.
Mendeleev Communications, 2016
8.
Artem’ev A.V., Gusarova N.K., Malysheva S.F., Belogorlova N.A., Kazheva O.N., Alexandrov G.G., Dyachenko O.A., Trofimov B.A.
Mendeleev Communications, 2015
9.
Gusarova N.K., Volkov P.A., Ivanova N.I., Khrapova K.O., Telezhkin A.A., Albanov A.I., Trofimov B.A.
Mendeleev Communications, 2017
10.
Expedient one-pot organometallics-free synthesis of tris(2-pyridyl)phosphine from 2-bromopyridine and elemental phosphorus
Trofimov B.A., Artem’ev A.V., Malysheva S.F., Gusarova N.K., Belogorlova N.A., Korocheva A.O., Gatilov Y.V., Mamatyuk V.I.
Tetrahedron Letters, 2012
11.
A new class of luminescent Cu(i) complexes with tripodal ligands – TADF emitters for the yellow to red color range
Gneuß T., Leitl M.J., Finger L.H., Rau N., Yersin H., Sundermeyer J.
Dalton Transactions, 2015
13.
Factors Impacting Electron Transfer in Cyano-Bridged {Fe2Co2} Clusters
Zheng C., Xu J., Yang Z., Tao J., Li D.
Inorganic Chemistry, 2015
16.
Polymorphism in Fe[(p-IC6H4)B(3-Mepz)3]2 (pz = Pyrazolyl):  Impact of Supramolecular Structure on an Iron(II) Electronic Spin-State Crossover
Reger D.L., Gardinier J.R., Smith M.D., Shahin A.M., Long G.J., Rebbouh L., Grandjean F.
Inorganic Chemistry, 2005
17.
A Study of the Electronic Spin‐State Crossover in {Fe[HC(3,4,5‐Me 3 pz) 3 ] 2 }(BF 4 ) 2
Reger D., Elgin J. ., Smith M., Grandjean F., Rebbouh L., Long G.
European Journal of Inorganic Chemistry, 2004
18.
The reaction of red phosphorus with 1-bromonaphthalene in the KOH-DMSO system: Synthesis of tri(1-naphthyl)phosphane
Kuimov V.A., Malysheva S.F., Gusarova N.K., Vakul'skaya T.I., Khutsishvili S.S., Trofimov B.A.
Heteroatom Chemistry, 2011
19.
First example of the $$ C_{sp^2 } $$ -P bond formation in the reaction of red phosphorus with hetaryl halides
Malysheva S.F., Artem’ev A.V., Belogorlova N.A., Korocheva A.O., Gusarova N.K., Trofimov B.A.
Russian Journal of General Chemistry, 2012
20.
Synthesis, Characterization, and Crystal Structures of Tris(2-pyridyl)phosphine Sulfide and Selenide
Kharat A.N., Bakhoda A., Hajiashrafi T., Abbasi A.
Phosphorus, Sulfur and Silicon and the Related Elements, 2010
21.
Crystal structure of Bis(tri-2-pyridylamine)iron(II) diperchlorate
Kucharski E., McWhinnie W., White A.
Australian Journal of Chemistry, 1978
22.
Synthesis and coordination chemistry of 1,1,1-tris-(pyrid-2-yl)ethane
Santoro A., Sambiagio C., McGowan P.C., Halcrow M.A.
Dalton Transactions, 2015
23.
Structures and spectra of bis-tripodal iron(II) chelates, [FeL2]2+, where L = tris(pyrazol-1-yl)methane, tris(pyridin-2-yl)methane, bis(pyrazol-1-yl)(pyridin-2-yl)methane and tris(pyridin-2-yl)phosphine oxide. Magnetism and spin crossover in the (pz)3CH case
Anderson P.A., Astley T., Hitchman M.A., Keene F.R., Moubaraki B., Murray K.S., Skelton B.W., Tiekink E.R., Toftlund H., White A.H.
Journal of the Chemical Society Dalton Transactions, 2000
24.
Spin crossover in di-, tri- and tetranuclear, mixed-ligand tris(pyrazolyl)methane iron(ii) complexes
Schneider C.J., Moubaraki B., Cashion J.D., Turner D.R., Leita B.A., Batten S.R., Murray K.S.
Dalton Transactions, 2011
25.
Molecular Structure and Magnetic Properties of Pentapyridyl-based Iron(II) and Cobalt(II) Complexes
Lee Y.H., Kato K., Kubota E., Kawata S., Hayami S.
Chemistry Letters, 2012
26.
Magnetic Properties of Iron(II) and Cobalt(II) Complexes of Tetrakis(2-pyridyl)methane. Spin-crossover Behavior in the Cobalt(II) Complex
Ishikawa R., Matsumoto K., Onishi K., Kubo T., Fuyuhiro A., Hayami S., Inoue K., Kaizaki S., Kawata S.
Chemistry Letters, 2009