Home / Publications / PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics

PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics

,  , 
Galina Olegovna Bragina 1
Galina Olegovna Bragina
, 
Galina Nikolaevna Baeva 1
Galina Nikolaevna Baeva
, 
Alexander Viktorovich Rassolov 1
Alexander Viktorovich Rassolov
, 
Andrey Valerievich Bukhtiyarov 2
Andrey Valerievich Bukhtiyarov
, 
Igor P Prosvirin 2
Igor P Prosvirin
, 
Valerii Ivanovich Bukhtiyarov 2
Valerii Ivanovich Bukhtiyarov
, 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
10.1016/j.mencom.2018.03.014
Published 2018-03-01
Communication , Volume 28, Issue 2, 152-154
30
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Mashkovsky I. S. et al. PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics // Mendeleev Communications. 2018. Vol. 28. No. 2. pp. 152-154.
GOST all authors (up to 50) Copy
Mashkovsky I. S., Markov P. V., Bragina G. O., Baeva G. N., Rassolov A. V., Bukhtiyarov A. V., Prosvirin I. P., Bukhtiyarov V. I., Stakheev A. Y. PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics // Mendeleev Communications. 2018. Vol. 28. No. 2. pp. 152-154.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2018.03.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.014
TI - PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics
T2 - Mendeleev Communications
AU - Mashkovsky, Igor' Sergeevich
AU - Markov, Pavel Viktorovich
AU - Bragina, Galina Olegovna
AU - Baeva, Galina Nikolaevna
AU - Rassolov, Alexander Viktorovich
AU - Bukhtiyarov, Andrey Valerievich
AU - Prosvirin, Igor P
AU - Bukhtiyarov, Valerii Ivanovich
AU - Stakheev, Aleksandr Yurevich
PY - 2018
DA - 2018/03/01
PB - Mendeleev Communications
SP - 152-154
IS - 2
VL - 28
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Mashkovsky,
author = {Igor' Sergeevich Mashkovsky and Pavel Viktorovich Markov and Galina Olegovna Bragina and Galina Nikolaevna Baeva and Alexander Viktorovich Rassolov and Andrey Valerievich Bukhtiyarov and Igor P Prosvirin and Valerii Ivanovich Bukhtiyarov and Aleksandr Yurevich Stakheev},
title = {PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.014},
number = {2},
pages = {152--154},
doi = {10.1016/j.mencom.2018.03.014}
}
MLA
Cite this
MLA Copy
Mashkovsky, Igor' Sergeevich, et al. “PdZn/α-Al2O3 catalyst for liquid-phase alkyne hydrogenation: effect of the solid-state alloy transformation into intermetallics.” Mendeleev Communications, vol. 28, no. 2, Mar. 2018, pp. 152-154. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.03.014.

Abstract

The complex characterization of a PdZn /Al2O3 catalyst by XPS, XRD, TEM and H2-TPD techniques revealed the route of solid-state alloy → intermetallics transformation. The influence of this transformation on the performance of PdZn /Al2O3 in the liquid-phase hydrogenation of diphenylacetylene was estimated.

References

2.
Ananikov V.P., Galkin K.I., Egorov M.P., Sakharov A.M., Zlotin S.G., Redina E.A., Isaeva V.I., Kustov L.M., Gening M.L., Nifantiev N.E.
Mendeleev Communications, 2016
3.
Ananikov V.P., Eremin D.B., Yakukhnov S.A., Dilman A.D., Levin V.V., Egorov M.P., Karlov S.S., Kustov L.M., Tarasov A.L., Greish A.A., Shesterkina A.A., Sakharov A.M., Nysenko Z.N., Sheremetev A.B., Stakheev A.Y., et. al.
Mendeleev Communications, 2017
4.
Nartova A.V., Kovtunova L.M., Larichev Y.V., Khudorozhkov A.K., Bobrovskaya A.N., Shterk G.V., Bukhtiyarov V.I.
Mendeleev Communications, 2017
5.
Markov P.V., Bragina G.O., Rassolov A.V., Mashkovsky I.S., Baeva G.N., Tkachenko O.P., Yakushev I.A., Vargaftik M.N., Stakheev A.Y.
Mendeleev Communications, 2016
6.
Markov P.V., Bragina G.O., Rassolov A.V., Baeva G.N., Mashkovsky I.S., Murzin V.Y., Zubavichus Y.V., Stakheev A.Y.
Mendeleev Communications, 2016
7.
Intermetallic Nanocrystals: Syntheses and Catalytic Applications
Yan Y., Du J.S., Gilroy K.D., Yang D., Xia Y., Zhang H.
Advanced Materials, 2017
11.
The Intermetallic Compound ZnPd and Its Role in Methanol Steam Reforming
Armbrüster M., Behrens M., Föttinger K., Friedrich M., Gaudry É., Matam S.K., Sharma H.R.
Catalysis Reviews - Science and Engineering, 2013
12.
Formation of supported intermetallic nanoparticles in the Pd–Zn/α-Al2O3 catalyst
Mashkovsky I.S., Markov P.V., Bragina G.O., Baeva G.N., Bukhtiyarov A.V., Prosvirin I.P., Bukhtiyarov V.I., Stakheev A.Y.
Kinetics and Catalysis, 2017
13.
PdZn Intermetallic Nanostructure with Pd–Zn–Pd Ensembles for Highly Active and Chemoselective Semi-Hydrogenation of Acetylene
Zhou H., Yang X., Li L., Liu X., Huang Y., Pan X., Wang A., Li J., Zhang T.
ACS Catalysis, 2016
14.
Chemical synthesis of blue-emitting metallic zinc nano-hexagons
Mai N.T., Thuy T.T., Mott D.M., Maenosono S.
CrystEngComm, 2013
15.
PdZn Surface Alloys as Models of Methanol Steam Reforming Catalysts: Molecular Studies by LEED, XPS, TPD and PM-IRAS
Holzapfel H.H., Wolfbeisser A., Rameshan C., Weilach C., Rupprechter G.
Topics in Catalysis, 2014
16.
Pd/ZnO catalysts for direct CO2 hydrogenation to methanol
Bahruji H., Bowker M., Hutchings G., Dimitratos N., Wells P., Gibson E., Jones W., Brookes C., Morgan D., Lalev G.
Journal of Catalysis, 2016
18.
Steam reforming of methanol over Pd/ZnO: Effect of the formation of PdZn alloys upon the reaction
Iwasa N., Masuda S., Ogawa N., Takezawa N.
Applied Catalysis A: General, 1995
19.
In situ Raman and in situ XRD analysis of PdO reduction and Pd° oxidation supported on γ-Al2O3 catalyst under different atmospheres
Baylet A., Marécot P., Duprez D., Castellazzi P., Groppi G., Forzatti P.
Physical Chemistry Chemical Physics, 2011
20.
AZO Thin Films by Sol-Gel Process for Integrated Optics
Znaidi L., Touam T., Vrel D., Souded N., Yahia S., Brinza O., Fischer A., Boudrioua A.
Coatings, 2013
21.
10.1016/j.mencom.2018.03.014_bib0105
Akhtar
Int. J. Nanomedicine, 2012
22.
PdZn catalysts for CO2 hydrogenation to methanol using chemical vapour impregnation (CVI)
Bahruji H., Bowker M., Jones W., Hayward J., Ruiz Esquius J., Morgan D.J., Hutchings G.J.
Faraday Discussions, 2017
23.
P. S. da Silva, J.M. Maciel, K. Wohnrath, A. Spinelli and J. R. Garcia, in Modern Surface Engineering Treatments, ed. M. Aliofkhazraei, InTech, 2013, ch. 9, pp. 209-230.
24.
Investigation of PdZn nanoparticle formation upon the thermal decomposition of acetate precursors by in situ XRD and XAFS
Veligzhanin A.A., Zubavichus Y.V., Kozitsyna N.Y., Murzin V.Y., Khramov E.V., Chernyshov A.A.
Journal of Surface Investigation, 2013
25.
Temperature-Induced Modifications of PdZn Layers on Pd(111)
Stadlmayr W., Rameshan C., Weilach C., Lorenz H., Hävecker M., Blume R., Rocha T., Teschner D., Knop-Gericke A., Zemlyanov D., Penner S., Schlögl R., Rupprechter G., Klötzer B., Memmel N., et. al.
Journal of Physical Chemistry C, 2010
28.
10.1016/j.mencom.2018.03.014_bib0140
Arnold
Handbook of Heterogeneous Catalysis, 2008
30.
Catalytic hydrogenation of alkyne and alkadiene impurities from alkenes. Practical and theoretical aspects
Nikolaev S.A., Zanaveskin L.N., Smirnov V.V., Averyanov V.A., Zanaveskin K.L.
Russian Chemical Reviews, 2009
31.
Supported catalysts based on Pd–In nanoparticles for the liquid-phase hydrogenation of terminal and internal alkynes: 1. formation and structure
Markov P.V., Bragina G.O., Baeva G.N., Tkachenko O.P., Mashkovskii I.S., Yakushev I.A., Vargaftik M.N., Stakheev A.Y.
Kinetics and Catalysis, 2016
32.
How to Control the Selectivity of Palladium-based Catalysts in Hydrogenation Reactions: The Role of Subsurface Chemistry
Armbrüster M., Behrens M., Cinquini F., Föttinger K., Grin Y., Haghofer A., Klötzer B., Knop-Gericke A., Lorenz H., Ota A., Penner S., Prinz J., Rameshan C., Révay Z., Rosenthal D., et. al.
ChemCatChem, 2012