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Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

Sergei Andreevich Lermontov 1
Sergei Andreevich Lermontov
, 
Alena Nikolaevna Malkova 1
Alena Nikolaevna Malkova
, 
Nataliya Aleksandrovna Sipyagina 1
Nataliya Aleksandrovna Sipyagina
, 
Alexey Vladimirovich Semakov 1
Alexey Vladimirovich Semakov
, 
Aleksandr Yevgen'evich Baranchikov 2
Aleksandr Yevgen'evich Baranchikov
, 
Vladimir Konstantinovich Ivanov 2, 3
Vladimir Konstantinovich Ivanov
10.1016/j.mencom.2018.01.035
Published 2017-12-22
Communication , Volume 28, Issue 1, 102-104
5
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Lermontov S. A. et al. Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 102-104.
GOST all authors (up to 50) Copy
Lermontov S. A., Malkova A. N., Sipyagina N. A., Semakov A. V., Baranchikov A. Y., Ivanov V. K. Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 102-104.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.035
TI - Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels
T2 - Mendeleev Communications
AU - Lermontov, Sergei Andreevich
AU - Malkova, Alena Nikolaevna
AU - Sipyagina, Nataliya Aleksandrovna
AU - Semakov, Alexey Vladimirovich
AU - Baranchikov, Aleksandr Yevgen'evich
AU - Ivanov, Vladimir Konstantinovich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 102-104
IS - 1
VL - 28
ER -
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@article{2017_Lermontov,
author = {Sergei Andreevich Lermontov and Alena Nikolaevna Malkova and Nataliya Aleksandrovna Sipyagina and Alexey Vladimirovich Semakov and Aleksandr Yevgen'evich Baranchikov and Vladimir Konstantinovich Ivanov},
title = {Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.035},
number = {1},
pages = {102--104},
doi = {10.1016/j.mencom.2018.01.035}
}
MLA
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Lermontov, Sergei Andreevich, et al. “Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 102-104. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.035.

Abstract

Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde– resorcinol interaction.

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