Home / Publications / New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent

New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent

Maxim Vyacheslavovich Arsenyev 1
Maxim Vyacheslavovich Arsenyev
, 
Tatyana Vadimovna Astaf'eva 1
Tatyana Vadimovna Astaf'eva
, 
Eugeny Vladimirovich Baranov 1
Eugeny Vladimirovich Baranov
, 
Andrey Igorevich Poddel'sky 1
Andrey Igorevich Poddel'sky
, 
Sergey Arturovich Chesnokov 1
Sergey Arturovich Chesnokov
10.1016/j.mencom.2018.01.025
Published 2017-12-22
Communication , Volume 28, Issue 1, 76-78
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Arsenyev M. V. et al. New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 76-78.
GOST all authors (up to 50) Copy
Arsenyev M. V., Astaf'eva T. V., Baranov E. V., Poddel'sky A. I., Chesnokov S. A. New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 76-78.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.025
TI - New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent
T2 - Mendeleev Communications
AU - Arsenyev, Maxim Vyacheslavovich
AU - Astaf'eva, Tatyana Vadimovna
AU - Baranov, Eugeny Vladimirovich
AU - Poddel'sky, Andrey Igorevich
AU - Chesnokov, Sergey Arturovich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 76-78
IS - 1
VL - 28
ER -
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@article{2017_Arsenyev,
author = {Maxim Vyacheslavovich Arsenyev and Tatyana Vadimovna Astaf'eva and Eugeny Vladimirovich Baranov and Andrey Igorevich Poddel'sky and Sergey Arturovich Chesnokov},
title = {New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.025},
number = {1},
pages = {76--78},
doi = {10.1016/j.mencom.2018.01.025}
}
MLA
Cite this
MLA Copy
Arsenyev, Maxim Vyacheslavovich, et al. “New sterically hindered bis-catechol, bis-o-quinone and its bis-triphenylantimony(v) bis-catecholate. 3,5-Di-tert-butyl-6-methoxymethylcatechol as alkylating agent.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 76-78. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.025.

Abstract

Alkylation of 1,3,5-trimethoxybenzene with 3,5-di-tert-butyl-6-methoxymethylcatechol affords new sterically hindered biscatechol, whose oxidation gives the corresponding bis-o-quinone. Its treatment with triphenylstibine leads to bis-triphenylantimony(v) bis-catecholate.

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