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Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization

Boris Andreevich Lozhkin 1
Boris Andreevich Lozhkin
, 
Andrei Vladimirovich Shlyakhtin 1
Andrei Vladimirovich Shlyakhtin
, 
Vladimir Vladimirovich Bagrov 1
Vladimir Vladimirovich Bagrov
, 
Pavel Vasil'evich Ivchenko 1, 2
Pavel Vasil'evich Ivchenko
, 
Ilya Eduardovich Nifant'ev 1, 2
Ilya Eduardovich Nifant'ev
10.1016/j.mencom.2018.01.020
Published 2017-12-22
Communication , Volume 28, Issue 1, 61-63
24
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Lozhkin B. A. et al. Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 61-63.
GOST all authors (up to 50) Copy
Lozhkin B. A., Shlyakhtin A. V., Bagrov V. V., Ivchenko P. V., Nifant'ev I. E. Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 61-63.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.020
TI - Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization
T2 - Mendeleev Communications
AU - Lozhkin, Boris Andreevich
AU - Shlyakhtin, Andrei Vladimirovich
AU - Bagrov, Vladimir Vladimirovich
AU - Ivchenko, Pavel Vasil'evich
AU - Nifant'ev, Ilya Eduardovich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 61-63
IS - 1
VL - 28
ER -
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@article{2017_Lozhkin,
author = {Boris Andreevich Lozhkin and Andrei Vladimirovich Shlyakhtin and Vladimir Vladimirovich Bagrov and Pavel Vasil'evich Ivchenko and Ilya Eduardovich Nifant'ev},
title = {Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.020},
number = {1},
pages = {61--63},
doi = {10.1016/j.mencom.2018.01.020}
}
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Lozhkin, Boris Andreevich, et al. “Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 61-63. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.020.

Abstract

Intramolecular cyclization of α-bromoacyl derivatives of α-hydroxy acids affords 1,4-dioxane-2,5-diones. The method is suitable to obtain mono- and disubstituted products, the latter being formed stereoselectively as (S,S)-diastereomers, as confirmed by DFT modeling.

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