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Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system

Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Ivan A. Bidusenko 1
Ivan A. Bidusenko
, 
Natalia Aleksandrovna Cherimichkina 1
Natalia Aleksandrovna Cherimichkina
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2018.01.015
Published 2017-12-22
Communication , Volume 28, Issue 1, 47-48
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Schmidt E. Y. et al. Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 47-48.
GOST all authors (up to 50) Copy
Schmidt E. Y., Bidusenko I. A., Cherimichkina N. A., Trofimov B. A. Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 47-48.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.015
TI - Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system
T2 - Mendeleev Communications
AU - Schmidt, Elena Yur'evna
AU - Bidusenko, Ivan A.
AU - Cherimichkina, Natalia Aleksandrovna
AU - Trofimov, Boris Aleksandrovich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 47-48
IS - 1
VL - 28
ER -
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@article{2017_Schmidt,
author = {Elena Yur'evna Schmidt and Ivan A. Bidusenko and Natalia Aleksandrovna Cherimichkina and Boris Aleksandrovich Trofimov},
title = {Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.015},
number = {1},
pages = {47--48},
doi = {10.1016/j.mencom.2018.01.015}
}
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Schmidt, Elena Yur'evna, et al. “Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 47-48. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.015.

Abstract

Acetylene reacts with chalcones in the NaOBut / DMSO superbase system (3–12 atm, 70°C, 15 min) to give, along with substituted furans, functionalized 3-exo-aryl-7-methylidene- 6,8-dioxabicyclo[3.2.1]octanes, novel frontalin congeners, which are diastereoselectively assembled from two molecules of chalcones and one molecule of acetylene.

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