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A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features

Sergey Alexandrovich Adonin 1, 2
Sergey Alexandrovich Adonin
, 
Igor D Gorokh 2
Igor D Gorokh
, 
Pavel Aleksandrovich Abramov 1, 2
Pavel Aleksandrovich Abramov
, 
Ilya Victorovich Korolkov 1, 2
Ilya Victorovich Korolkov
, 
Maksim Nail'evich Sokolov 1, 3
Maksim Nail'evich Sokolov
, 
Vladimir Petrovich Fedin 1, 2
Vladimir Petrovich Fedin
10.1016/j.mencom.2018.01.012
Published 2017-12-22
Communication , Volume 28, Issue 1, 39-40
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Adonin S. A. et al. A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 39-40.
GOST all authors (up to 50) Copy
Adonin S. A., Gorokh I. D., Abramov P. A., Korolkov I. V., Sokolov M. N., Fedin V. P. A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 39-40.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.012
TI - A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features
T2 - Mendeleev Communications
AU - Adonin, Sergey Alexandrovich
AU - Gorokh, Igor D
AU - Abramov, Pavel Aleksandrovich
AU - Korolkov, Ilya Victorovich
AU - Sokolov, Maksim Nail'evich
AU - Fedin, Vladimir Petrovich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 39-40
IS - 1
VL - 28
ER -
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@article{2017_Adonin,
author = {Sergey Alexandrovich Adonin and Igor D Gorokh and Pavel Aleksandrovich Abramov and Ilya Victorovich Korolkov and Maksim Nail'evich Sokolov and Vladimir Petrovich Fedin},
title = {A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.012},
number = {1},
pages = {39--40},
doi = {10.1016/j.mencom.2018.01.012}
}
MLA
Cite this
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Adonin, Sergey Alexandrovich, et al. “A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 39-40. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.012.

Abstract

The polybromide complex (Et4N)3{[Bi2Br9](Br2)} was obtained by reaction of [BiBr6]3–, Br2 and tetraethylammonium bromide in 2 m HBr. In its crystal structure, bioctahedral [Bi2Br9]3– anions are connected by neutral Br2 linkers into infinite 1D chains via terminal bromide ligands.

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