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Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions

Alexander Mikhailovich Genaev 1
Alexander Mikhailovich Genaev
, 
Georgii Efimovich Salnikov 1, 2
Georgii Efimovich Salnikov
, 
Andrey Vladimirovich Shernyukov 1
Andrey Vladimirovich Shernyukov
, 
Zhongwei Zhu 2
Zhongwei Zhu
, 
Konstantin Yurievich Koltunov 2, 3
Konstantin Yurievich Koltunov
10.1016/j.mencom.2018.01.007
Published 2017-12-22
Communication , Volume 28, Issue 1, 27-28
4
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Genaev A. M. et al. Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 27-28.
GOST all authors (up to 50) Copy
Genaev A. M., Salnikov G. E., Shernyukov A. V., Zhu Z., Koltunov K. Y. Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions // Mendeleev Communications. 2017. Vol. 28. No. 1. pp. 27-28.
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TY - JOUR
DO - 10.1016/j.mencom.2018.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.007
TI - Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions
T2 - Mendeleev Communications
AU - Genaev, Alexander Mikhailovich
AU - Salnikov, Georgii Efimovich
AU - Shernyukov, Andrey Vladimirovich
AU - Zhu, Zhongwei
AU - Koltunov, Konstantin Yurievich
PY - 2017
DA - 2017/12/22
PB - Mendeleev Communications
SP - 27-28
IS - 1
VL - 28
ER -
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@article{2017_Genaev,
author = {Alexander Mikhailovich Genaev and Georgii Efimovich Salnikov and Andrey Vladimirovich Shernyukov and Zhongwei Zhu and Konstantin Yurievich Koltunov},
title = {Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions},
journal = {Mendeleev Communications},
year = {2017},
volume = {28},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.007},
number = {1},
pages = {27--28},
doi = {10.1016/j.mencom.2018.01.007}
}
MLA
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MLA Copy
Genaev, Alexander Mikhailovich, et al. “Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions.” Mendeleev Communications, vol. 28, no. 1, Dec. 2017, pp. 27-28. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2018.01.007.

Abstract

Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1sp3 –C1'sp3 bond in its protonatedforms.

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