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Solvent-free Buchwald–Hartwig amination with low palladium loadings

,  ,  ,  , 
Andrey Fedorovich Asachenko 2, 3
Andrey Fedorovich Asachenko
,  , 
Evgeniya Vladimirovna Bermesheva 1, 4
Evgeniya Vladimirovna Bermesheva
, 
Maksim Vladimirovich Bermeshev 2
Maksim Vladimirovich Bermeshev
10.1016/j.mencom.2017.11.027
Published 2017-10-30
Communication , Volume 27, Issue 6, 618-620
26
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Chesnokov G. A. et al. Solvent-free Buchwald–Hartwig amination with low palladium loadings // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 618-620.
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Chesnokov G. A., Gribanov P. S., Topchiy M. A., Minaeva L. I., Asachenko A. F., Nechaev M. S., Bermesheva E. V., Bermeshev M. V. Solvent-free Buchwald–Hartwig amination with low palladium loadings // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 618-620.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.027
TI - Solvent-free Buchwald–Hartwig amination with low palladium loadings
T2 - Mendeleev Communications
AU - Chesnokov, Gleb Andreevich
AU - Gribanov, Pavel Sergeevich
AU - Topchiy, Maxim Anatol'evich
AU - Minaeva, Lidiya Igorevna
AU - Asachenko, Andrey Fedorovich
AU - Nechaev, M S
AU - Bermesheva, Evgeniya Vladimirovna
AU - Bermeshev, Maksim Vladimirovich
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 618-620
IS - 6
VL - 27
ER -
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@article{2017_Chesnokov,
author = {Gleb Andreevich Chesnokov and Pavel Sergeevich Gribanov and Maxim Anatol'evich Topchiy and Lidiya Igorevna Minaeva and Andrey Fedorovich Asachenko and M S Nechaev and Evgeniya Vladimirovna Bermesheva and Maksim Vladimirovich Bermeshev},
title = {Solvent-free Buchwald–Hartwig amination with low palladium loadings},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.027},
number = {6},
pages = {618--620},
doi = {10.1016/j.mencom.2017.11.027}
}
MLA
Cite this
MLA Copy
Chesnokov, Gleb Andreevich, et al. “Solvent-free Buchwald–Hartwig amination with low palladium loadings.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 618-620. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.027.

Abstract

A highly efficient ‘green’ solvent-free monoarylation of primary anilines with aryl bromides mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp is 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn is cinnamyl] can be performed at low catalyst loadings (0.1 mol%) to provide excellent yields and remarkable selectivities for various substrates.

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