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Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study

Alexander Viktorovich Rassolov 1
Alexander Viktorovich Rassolov
, 
Dmitry Sergeevich Krivoruchenko 1
Dmitry Sergeevich Krivoruchenko
,  ,  , 
Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
, 
Igor Svitanko 1
Igor Svitanko
10.1016/j.mencom.2017.11.026
Published 2017-10-30
Communication , Volume 27, Issue 6, 615-617
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Rassolov A. V. et al. Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 615-617.
GOST all authors (up to 50) Copy
Rassolov A. V., Krivoruchenko D. S., Medvedev M. G., Mashkovsky I. S., Stakheev A. Y., Svitanko I. Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 615-617.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.026
TI - Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study
T2 - Mendeleev Communications
AU - Rassolov, Alexander Viktorovich
AU - Krivoruchenko, Dmitry Sergeevich
AU - Medvedev, Michael G
AU - Mashkovsky, Igor' Sergeevich
AU - Stakheev, Aleksandr Yurevich
AU - Svitanko, Igor
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 615-617
IS - 6
VL - 27
ER -
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@article{2017_Rassolov,
author = {Alexander Viktorovich Rassolov and Dmitry Sergeevich Krivoruchenko and Michael G Medvedev and Igor' Sergeevich Mashkovsky and Aleksandr Yurevich Stakheev and Igor Svitanko},
title = {Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.026},
number = {6},
pages = {615--617},
doi = {10.1016/j.mencom.2017.11.026}
}
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Rassolov, Alexander Viktorovich, et al. “Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 615-617. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.026.

Abstract

The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.

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