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π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies

Olga Vladimirovna Shabunina 1
Olga Vladimirovna Shabunina
, 
Daria Yu Kapustina 1
Daria Yu Kapustina
, 
Alexey P Krinochkin 1
Alexey P Krinochkin
, 
Grigory Andreevich Kim 1, 2
Grigory Andreevich Kim
, 
Dmitrii Sergeevich Kopchuk 1, 2
Dmitrii Sergeevich Kopchuk
, 
Grigory Vasil'evich Zyryanov 1, 2
Grigory Vasil'evich Zyryanov
, 
Fengyu Li 3
Fengyu Li
, 
Oleg Nikolaevich Chupakhin 1, 2
Oleg Nikolaevich Chupakhin
10.1016/j.mencom.2017.11.021
Published 2017-10-30
Communication , Volume 27, Issue 6, 602-604
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Shabunina O. V. et al. π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 602-604.
GOST all authors (up to 50) Copy
Shabunina O. V., Kapustina D. Yu., Krinochkin A. P., Kim G. A., Kopchuk D. S., Zyryanov G. V., Li F., Chupakhin O. N. π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 602-604.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.021
TI - π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies
T2 - Mendeleev Communications
AU - Shabunina, Olga Vladimirovna
AU - Kapustina, Daria Yu
AU - Krinochkin, Alexey P
AU - Kim, Grigory Andreevich
AU - Kopchuk, Dmitrii Sergeevich
AU - Zyryanov, Grigory Vasil'evich
AU - Li, Fengyu
AU - Chupakhin, Oleg Nikolaevich
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 602-604
IS - 6
VL - 27
ER -
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@article{2017_Shabunina,
author = {Olga Vladimirovna Shabunina and Daria Yu Kapustina and Alexey P Krinochkin and Grigory Andreevich Kim and Dmitrii Sergeevich Kopchuk and Grigory Vasil'evich Zyryanov and Fengyu Li and Oleg Nikolaevich Chupakhin},
title = {π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.021},
number = {6},
pages = {602--604},
doi = {10.1016/j.mencom.2017.11.021}
}
MLA
Cite this
MLA Copy
Shabunina, Olga Vladimirovna, et al. “π-Extended fluorophores based on 5-aryl-2,2’-bipyridines: synthesis and photophysical studies.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 602-604. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.021.

Abstract

A straightforward and convenient synthesis of new fluorescent 5-aryl-2,2’-bipyridines with the extended conjugation system involves the ‘1,2,4-triazine’ methodology followed by Pd- catalyzed cross-coupling or Wittig reactions using 5-(4-bromo- phenyl)- or 5-(4-bromomethylphenyl)-2,2’-bipyridines as the starting materials. For these compounds, a pronounced bathochromic shift was observed in both absorption and emission spectra compared to previously reported 5-phenyl- 2,2’-bipyridine. For the one of the products, adsorption and fluorescent titrations were fulfilled, fluorescent response on the addition of metal cations was examined.

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