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Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene

Vladimir Alekseevich Kokorekin 1
Vladimir Alekseevich Kokorekin
, 
Yaroslav A Solomatin 1
Yaroslav A Solomatin
, 
Marina Leonidovna Gening 1
Marina Leonidovna Gening
, 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2017.11.016
Published 2017-10-30
Communication , Volume 27, Issue 6, 586-588
7
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Kokorekin V. A. et al. Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 586-588.
GOST all authors (up to 50) Copy
Kokorekin V. A., Solomatin Y. A., Gening M. L., Petrosyan V. A. Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 586-588.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.016
TI - Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene
T2 - Mendeleev Communications
AU - Kokorekin, Vladimir Alekseevich
AU - Solomatin, Yaroslav A
AU - Gening, Marina Leonidovna
AU - Petrosyan, Vladimir Anushavanovich
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 586-588
IS - 6
VL - 27
ER -
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@article{2017_Kokorekin,
author = {Vladimir Alekseevich Kokorekin and Yaroslav A Solomatin and Marina Leonidovna Gening and Vladimir Anushavanovich Petrosyan},
title = {Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.016},
number = {6},
pages = {586--588},
doi = {10.1016/j.mencom.2017.11.016}
}
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Kokorekin, Vladimir Alekseevich, et al. “Acid-catalyzed \( \mathrm{S_N^H (An)} \) thiolation of p-dihydroxybenzene.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 586-588. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.016.
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Abstract

The anodic functionalization of p-dihydroxybenzene with poorly nucleophilic thiols is performed by acid activation of p-quinone electrogenerated at the first stage followed by treatment with thiols at the second stage. This two-stage process is preferable in terms of efficiency.

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