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Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol

Andrei Semenovich Mendkovich 1
Andrei Semenovich Mendkovich
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Kristina R Mitina 1
Kristina R Mitina
, 
Mikhail Nikolaevich Mikhailov 1
Mikhail Nikolaevich Mikhailov
, 
Vadim Pavlovich Gul'tyai 1
Vadim Pavlovich Gul'tyai
, 
Valery Mikhailovich Pechennikov 2
Valery Mikhailovich Pechennikov
10.1016/j.mencom.2017.11.014
Published 2017-10-30
Communication , Volume 27, Issue 6, 580-582
9
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Mendkovich A. S. et al. Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 580-582.
GOST all authors (up to 50) Copy
Mendkovich A. S., Syroeshkin M. A., Mitina K. R., Mikhailov M. N., Gul'tyai V. P., Pechennikov V. M. Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol // Mendeleev Communications. 2017. Vol. 27. No. 6. pp. 580-582.
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TY - JOUR
DO - 10.1016/j.mencom.2017.11.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.014
TI - Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol
T2 - Mendeleev Communications
AU - Mendkovich, Andrei Semenovich
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Mitina, Kristina R
AU - Mikhailov, Mikhail Nikolaevich
AU - Gul'tyai, Vadim Pavlovich
AU - Pechennikov, Valery Mikhailovich
PY - 2017
DA - 2017/10/30
PB - Mendeleev Communications
SP - 580-582
IS - 6
VL - 27
ER -
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@article{2017_Mendkovich,
author = {Andrei Semenovich Mendkovich and Mikhail Aleksandrovich Syroeshkin and Kristina R Mitina and Mikhail Nikolaevich Mikhailov and Vadim Pavlovich Gul'tyai and Valery Mikhailovich Pechennikov},
title = {Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.014},
number = {6},
pages = {580--582},
doi = {10.1016/j.mencom.2017.11.014}
}
MLA
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Mendkovich, Andrei Semenovich, et al. “Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol.” Mendeleev Communications, vol. 27, no. 6, Oct. 2017, pp. 580-582. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.11.014.

Abstract

Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9’H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C9–C9’ bond rather than the C9–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives.

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