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Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling

Anna Alekseevna Ignatova 1
Anna Alekseevna Ignatova
, 
Alexey Vyacheslavovich Kozlov 1
Alexey Vyacheslavovich Kozlov
, 
Alexander Fedorovich Shestakov 1
Alexander Fedorovich Shestakov
, 
Alexander Vladimirovich Chernyak 1
Alexander Vladimirovich Chernyak
,  , 
Pavel Anatol'evich Troshin 1, 2
Pavel Anatol'evich Troshin
10.1016/j.mencom.2017.09.032
Published 2017-09-07
Communication , Volume 27, Issue 5, 524-526
5
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Ignatova A. A. et al. Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 524-526.
GOST all authors (up to 50) Copy
Ignatova A. A., Kozlov A. V., Shestakov A. F., Chernyak A. V., Yarmolenko O. V., Troshin P. A. Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 524-526.
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TY - JOUR
DO - 10.1016/j.mencom.2017.09.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.032
TI - Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling
T2 - Mendeleev Communications
AU - Ignatova, Anna Alekseevna
AU - Kozlov, Alexey Vyacheslavovich
AU - Shestakov, Alexander Fedorovich
AU - Chernyak, Alexander Vladimirovich
AU - Yarmolenko, Ol'ga Viktorovna
AU - Troshin, Pavel Anatol'evich
PY - 2017
DA - 2017/09/07
PB - Mendeleev Communications
SP - 524-526
IS - 5
VL - 27
ER -
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@article{2017_Ignatova,
author = {Anna Alekseevna Ignatova and Alexey Vyacheslavovich Kozlov and Alexander Fedorovich Shestakov and Alexander Vladimirovich Chernyak and Ol'ga Viktorovna Yarmolenko and Pavel Anatol'evich Troshin},
title = {Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.032},
number = {5},
pages = {524--526},
doi = {10.1016/j.mencom.2017.09.032}
}
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Ignatova, Anna Alekseevna, et al. “Insight in the degradation of polyquinone-based cathode material in lithium-organic battery under cycling.” Mendeleev Communications, vol. 27, no. 5, Sep. 2017, pp. 524-526. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.032.

Abstract

Electrochemical lithiation of organic polyquinone-based cathode material can occur irreversibly leading thus to a rapid deterioration of the battery performance. Carefully controlled degree of lithium intercalation within the defined charge/ discharge potential window provides a stable battery operation within 170 cycles with 100% coulombic efficiency. DFT calculations revealed that deep lithiation results in a strong conformational reorganization of the polymer domains leading to repeatable expansion and shrinkage of the electroactive material and a rapid loss of the cathode integrity.

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