Home / Publications / Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes

Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes

, 
Tatiana V Dubinina 1, 2
Tatiana V Dubinina
,  , 
Anton Dmitrievich Kosov 1
Anton Dmitrievich Kosov
, 
Denis A Pankratov 1
Denis A Pankratov
, 
Larisa Godvigovna Tomilova 1, 2
Larisa Godvigovna Tomilova
10.1016/j.mencom.2017.09.012
Published 2017-09-07
Communication , Volume 27, Issue 5, 466-469
9
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Burtsev I. D. et al. Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 466-469.
GOST all authors (up to 50) Copy
Burtsev I. D., Dubinina T. V., Platonova Y. B., Kosov A. D., Pankratov D. A., Tomilova L. G. Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 466-469.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2017.09.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.012
TI - Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes
T2 - Mendeleev Communications
AU - Burtsev, Ivan Dmitrievich
AU - Dubinina, Tatiana V
AU - Platonova, Yana Borisovna
AU - Kosov, Anton Dmitrievich
AU - Pankratov, Denis A
AU - Tomilova, Larisa Godvigovna
PY - 2017
DA - 2017/09/07
PB - Mendeleev Communications
SP - 466-469
IS - 5
VL - 27
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Burtsev,
author = {Ivan Dmitrievich Burtsev and Tatiana V Dubinina and Yana Borisovna Platonova and Anton Dmitrievich Kosov and Denis A Pankratov and Larisa Godvigovna Tomilova},
title = {Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.012},
number = {5},
pages = {466--469},
doi = {10.1016/j.mencom.2017.09.012}
}
MLA
Cite this
MLA Copy
Burtsev, Ivan Dmitrievich, et al. “Synthesis and spectral properties of iron(III) tetra-tert-butylphthalocyanine complexes.” Mendeleev Communications, vol. 27, no. 5, Sep. 2017, pp. 466-469. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.012.

Abstract

Two tetra-tert-butylphthalocyanine complexes of iron(III) were synthesized in high yields from the phthalocyanine ligand and iron(III) salts; the oxidation state of iron was confirmed by Mössbauer and EPR spectroscopy. The existence of an acid–base equilibrium during spectrophotometric titration was revealed. The t-BuPcFeCl complex catalyzed chlorination of benzene.

References

1.
Molecular Design Rule of Phthalocyanine Dyes for Highly Efficient Near‐IR Performance in Dye‐Sensitized Solar Cells
Kimura M., Nomoto H., Suzuki H., Ikeuchi T., Matsuzaki H., Murakami T.N., Furube A., Masaki N., Griffith M.J., Mori S.
Chemistry - A European Journal, 2013
3.
The key role of peripheral substituents in the chemistry of phthalocyanines and their analogs
Lukyanets E.A., Nemykin V.N.
Journal of Porphyrins and Phthalocyanines, 2010
4.
Synthesis of an Octa-tert-butylphthalocyanine: A Low-Aggregating and Photochemically Stable Photosensitizer
Gobo N.R., Brocksom T.J., Zukerman-Schpector J., de Oliveira K.T.
European Journal of Organic Chemistry, 2013
5.
Tomilova L.G., Ivanov A.V., Kostyuchenko I.V., Shulishov E.V., Nefedov O.M.
Mendeleev Communications, 2002
6.
Rationally Designed Phthalocyanines Having Their Main Absorption Band beyond 1000 nm
Kobayashi N., Furuyama T., Satoh K.
Journal of the American Chemical Society, 2011
7.
Zinc complexes of 3-(ethylthio)phenyl-substituted phthalocyanines and naphthalocyanine: Synthesis and investigation of physicochemical properties
Dubinina T.V., Tychinsky P.I., Borisova N.E., Maklakov S.S., Sedova M.V., Kosov A.D., Tomilova L.G., Zefirov N.S.
Dyes and Pigments, 2017
8.
Synthesis of phthalocyanines with an extended system of π-electron conjugation
Dubinina T.V., Tomilova L.G., Zefirov N.S.
Russian Chemical Reviews, 2013
9.
Electrochemical and spectroelectrochemical behavior of planar binuclear naphthalocyanines
Trashin S.A., Dubinina T.V., Fionov A.V., Tomilova L.G.
Journal of Porphyrins and Phthalocyanines, 2011
10.
MCD spectroscopy and TD-DFT calculations of a naphthalene-ring-bridged coplanar binuclear phthalocyanine dimer
Mack J., Liang X., Dubinina T.V., Tomilova L.G., Nyokong T., Kobayashi N.
Journal of Porphyrins and Phthalocyanines, 2013
11.
Phenyl-substituted planar binuclear phthalo- and naphthalocyanines: synthesis and investigation of physicochemical properties
Dubinina T.V., Trashin S.A., Borisova N.E., Boginskaya I.A., Tomilova L.G., Zefirov N.S.
Dyes and Pigments, 2012
12.
Synthesis and investigation of spectral and electrochemical properties of alkyl-substituted planar binuclear phthalocyanine complexes sharing a common naphthalene ring
Dubinina T.V., Ivanov A.V., Borisova N.E., Trashin S.A., Gurskiy S.I., Tomilova L.G., Zefirov N.S.
Inorganica Chimica Acta, 2010
13.
Synthesis and spectral properties of new planar binuclear phthalocyanines sharing the benzene ring
Tolbin A.Y., Pushkarev V.E., Tomilova L.G., Zefirov N.S.
Russian Chemical Bulletin, 2006
14.
A post-cyclotetramerization strategy towards novel binuclear phthalocyanine dimers
Wang K., Huang C., Pan H., Kobayashi N., Jiang J.
Inorganic Chemistry Frontiers, 2017
15.
Linear and Rectangular Trinuclear Phthalocyanines
Makarov S.G., Suvorova O.N., Litwinski C., Ermilov E.A., Röder B., Tsaryova O., Dülcks T., Wöhrle D.
European Journal of Inorganic Chemistry, 2007
16.
Synthesis of a Dinuclear Naphthalocyanine Analogue with Absorption in the NIR
Makarov S.G., Suvorova O.N., Schnurpfeil G., Wöhrle D.
European Journal of Inorganic Chemistry, 2010
20.
Kogan E.G., Ivanov A.V., Tomilova L.G., Zefirov N.S.
Mendeleev Communications, 2002
21.
Synthesis and spectral properties of nonclassical binuclear thienoporphyrazines
Dubinina T.V., Borisova N.E., Sedova M.V., Tomilova L.G., Furuyama T., Kobayashi N.
Dyes and Pigments, 2015
22.
Korolev V.V., Lomova T.N., Ramazanova A.G., Mozhzhukhina E.G.
Mendeleev Communications, 2016
23.
Heteroleptic naphthalo-phthalocyaninates of lutetium: synthesis and spectral and conductivity properties
Dubinina T.V., Kosov A.D., Petrusevich E.F., Maklakov S.S., Borisova N.E., Tomilova L.G., Zefirov N.S.
Dalton Transactions, 2015
24.
Sandwich Double-Decker Lanthanide(III) “Intracavity” Complexes Based on Clamshell-Type Phthalocyanine Ligands: Synthesis, Spectral, Electrochemical, and Spectroelectrochemical Investigations
Pushkarev V.E., Tolbin A.Y., Zhurkin F.E., Borisova N.E., Trashin S.A., Tomilova L.G., Zefirov N.S.
Chemistry - A European Journal, 2012
25.
Synthetic approaches to lanthanide complexes with tetrapyrrole type ligands
Pushkarev V.E., Tomilova L.G., Tomilov Y.V.
Russian Chemical Reviews, 2008
26.
A voyage into the synthesis and photophysics of homo- and heterobinuclear ensembles of phthalocyanines and porphyrins
de la Torre G., Bottari G., Sekita M., Hausmann A., Guldi D.M., Torres T.
Chemical Society Reviews, 2013
27.
Electrochemical and electrochromic properties of rare-earth metal diphthalocyanine complexes
Magdesieva T.V., Zhukov I.V., Tomilova L.G., Korenchenko O.V., Kalashnikova I.P., Butin K.P.
Russian Chemical Bulletin, 2001
28.
Plasmon-Induced Light Absorption of Phthalocyanine Layer in Hybrid Nanoparticles: Enhancement Factor and Effective Spectra
Zasedatelev A.V., Dubinina T.V., Krichevsky D.M., Krasovskii V.I., Gak V.Y., Pushkarev V.E., Tomilova L.G., Chistyakov A.A.
Journal of Physical Chemistry C, 2016
30.
Synthesis, structure and properties of coordination compounds of iron phthalocyanines and their analogues
Nemykin V.N., Tret'yakova I.N., Volkov S.V., Li V.D., Mekhryakova N.G., Kaliya O.L., Luk'yanets E.A.
Russian Chemical Reviews, 2000
31.
Phthalocyanine Metal Complexes in Catalysis
Sorokin A.B.
Chemical Reviews, 2013
32.
10.1016/j.mencom.2017.09.012_bib0160
Mikhalenko
Zh. Obshch. Khim., 1971
33.
Selective synthesis and spectroscopic properties of alkyl-substituted lanthanide(III) mono-, di-, and triphthalocyanines
Pushkarev V.E., Breusova M.O., Shulishov E.V., Tomilov Y.V.
Russian Chemical Bulletin, 2005
34.
Investigation of iron(III) complex with crown-porphyrin
Pankratov D.A., Dolzhenko V.D., Stukan R.A., Al Ansari Y.F., Savinkina E.V., Kiselev Y.M.
Hyperfine Interactions, 2011
38.
Binuclear iron complexes with acyclic Schiff bases based on 4-tert-butyl-2,6-diformylphenol: synthesis, properties, and use in catalytic partial oxidation of isobutane
Rodionova L.I., Borisova N.E., Smirnov A.V., Ordomsky V.V., Moiseeva A.A., Pankratov D.A.
Russian Chemical Bulletin, 2013
39.
Mössbauer spectroscopic study of an iron(III) complex with crown porphyrin
Pankratov D.A., Stukan R.A., Al’ Ansari Y.-., Savinkina E.V., Kiselev Y.M.
Russian Journal of Inorganic Chemistry, 2011
40.
Spin states in iron(III) phthalocyanines studied by Moessbauer, magnetic susceptibility, and ESR measurements
Kennedy B.J., Murray K.S., Zwack P.R., Homborg H., Kalz W.
Inorganic Chemistry, 1986
41.
Effects of Solvation on the Spin State of Iron(III) in 2,8,12,18-Tetrabutyl-3,7,13,17-tetramethyl-5,10-diazaporphyrinatoiron(III) Chloride
Stuzhin P.A., Nefedov S.E., Kumeev R.S., Ul-Haq A., Minin V.V., Ivanova S.S.
Inorganic Chemistry, 2010
42.
Oxidative catalytic evolution of redox- and spin-states of a Fe-phthalocyanine studied by EPR
Bletsa E., Solakidou M., Louloudi M., Deligiannakis Y.
Chemical Physics Letters, 2016