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A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes

Vera Ivanovna Filyakova 1
Vera Ivanovna Filyakova
, 
Nadezhda S Boltacheva 1
Nadezhda S Boltacheva
, 
Marina Gennadievna Pervova 1
Marina Gennadievna Pervova
, 
Nadezhda Vladimirovna Palysaeva 2
Nadezhda Vladimirovna Palysaeva
, 
Pavel Alexandrovich Slepukhin 1
Pavel Alexandrovich Slepukhin
, 
Aleksei Borisovich Sheremetev 2
Aleksei Borisovich Sheremetev
, 
10.1016/j.mencom.2017.09.011
Published 2017-09-07
Communication , Volume 27, Issue 5, 464-465
7
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Filyakova V. I. et al. A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 464-465.
GOST all authors (up to 50) Copy
Filyakova V. I., Boltacheva N. S., Pervova M. G., Palysaeva N. V., Slepukhin P. A., Sheremetev A. B., Charushin V. N. A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes // Mendeleev Communications. 2017. Vol. 27. No. 5. pp. 464-465.
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TY - JOUR
DO - 10.1016/j.mencom.2017.09.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.011
TI - A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes
T2 - Mendeleev Communications
AU - Filyakova, Vera Ivanovna
AU - Boltacheva, Nadezhda S
AU - Pervova, Marina Gennadievna
AU - Palysaeva, Nadezhda Vladimirovna
AU - Slepukhin, Pavel Alexandrovich
AU - Sheremetev, Aleksei Borisovich
AU - Charushin, Valery Nikolaevich
PY - 2017
DA - 2017/09/07
PB - Mendeleev Communications
SP - 464-465
IS - 5
VL - 27
ER -
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@article{2017_Filyakova,
author = {Vera Ivanovna Filyakova and Nadezhda S Boltacheva and Marina Gennadievna Pervova and Nadezhda Vladimirovna Palysaeva and Pavel Alexandrovich Slepukhin and Aleksei Borisovich Sheremetev and Valery Nikolaevich Charushin},
title = {A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.011},
number = {5},
pages = {464--465},
doi = {10.1016/j.mencom.2017.09.011}
}
MLA
Cite this
MLA Copy
Filyakova, Vera Ivanovna, et al. “A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes.” Mendeleev Communications, vol. 27, no. 5, Sep. 2017, pp. 464-465. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.09.011.

Abstract

A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)- 1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane- 1,2,3-trione 2-oxime has been determined by X-ray crystallography.

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