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Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group

Alexander Yur'evich Kostyukovich 1
Alexander Yur'evich Kostyukovich
, 
Dmitrii Ilyich D'yachikhin 1
Dmitrii Ilyich D'yachikhin
, 
Ivan Dmitrievich Grishin 2
Ivan Dmitrievich Grishin
, 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
, 
Alexander Fedorovich Smol'yakov 1
Alexander Fedorovich Smol'yakov
, 
Fedor Mikhailovich Dolgushin 1
Fedor Mikhailovich Dolgushin
, 
Dmitry Fedorovich Grishin 2
Dmitry Fedorovich Grishin
, 
Igor Timofeevich Chizhevsky 1
Igor Timofeevich Chizhevsky
, 
Elena Vladimirovna Balagurova 1
Elena Vladimirovna Balagurova
10.1016/j.mencom.2017.07.025
Published 2017-06-29
Communication , Volume 27, Issue 4, 392-393
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Kostyukovich A. Y. et al. Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 392-393.
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Kostyukovich A. Y., D'yachikhin D. I., Grishin I. D., Godovikov I. A., Smol'yakov A. F., Dolgushin F. M., Grishin D. F., Chizhevsky I. T., Balagurova E. V. Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 392-393.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.025
TI - Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group
T2 - Mendeleev Communications
AU - Kostyukovich, Alexander Yur'evich
AU - D'yachikhin, Dmitrii Ilyich
AU - Grishin, Ivan Dmitrievich
AU - Godovikov, Ivan Alexandrovich
AU - Smol'yakov, Alexander Fedorovich
AU - Dolgushin, Fedor Mikhailovich
AU - Grishin, Dmitry Fedorovich
AU - Chizhevsky, Igor Timofeevich
AU - Balagurova, Elena Vladimirovna
PY - 2017
DA - 2017/06/29
PB - Mendeleev Communications
SP - 392-393
IS - 4
VL - 27
ER -
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@article{2017_Kostyukovich,
author = {Alexander Yur'evich Kostyukovich and Dmitrii Ilyich D'yachikhin and Ivan Dmitrievich Grishin and Ivan Alexandrovich Godovikov and Alexander Fedorovich Smol'yakov and Fedor Mikhailovich Dolgushin and Dmitry Fedorovich Grishin and Igor Timofeevich Chizhevsky and Elena Vladimirovna Balagurova},
title = {Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.025},
number = {4},
pages = {392--393},
doi = {10.1016/j.mencom.2017.07.025}
}
MLA
Cite this
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Kostyukovich, Alexander Yur'evich, et al. “Synthesis and molecular structure of exo-nido-ruthenacarborane containing vinylene bridge group.” Mendeleev Communications, vol. 27, no. 4, Jun. 2017, pp. 392-393. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.025.

Abstract

The reaction of the ruthenacarborane exo-nido-5,6,10-[Cl(Ph3P)2Ru]-5,6,10-(m-H)3-10-H-7,8-(Ph)2-7,8-C2B9H6 with phenylacetylene in dichloromethane in the presence of triethylamine at ambient temperature affords exo-nido-5,6,10-[(Ph3P)2Ru]-5,6-(μ-H)2-10-[μ-(PhC=CH)]-10-H-7,8-(Ph)2-7,8-C2B9H6 containing vinylene bridge group between carborane framework and ruthenium atom. Structure of the complex has been determined by X-ray diffraction study.

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