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A new type of the dinitrogen pentoxide–acid interaction

Victor Petrovich Zelenov 1
Victor Petrovich Zelenov
, 
Sergei Sergeevich Bukalov 2
Sergei Sergeevich Bukalov
, 
Alexandr Nikolaevich Subbotin 1
Alexandr Nikolaevich Subbotin
10.1016/j.mencom.2017.07.011
Published 2017-06-29
Communication , Volume 27, Issue 4, 355-356
7
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Zelenov V. P., Bukalov S. S., Subbotin A. N. A new type of the dinitrogen pentoxide–acid interaction // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 355-356.
GOST all authors (up to 50) Copy
Zelenov V. P., Bukalov S. S., Subbotin A. N. A new type of the dinitrogen pentoxide–acid interaction // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 355-356.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.011
TI - A new type of the dinitrogen pentoxide–acid interaction
T2 - Mendeleev Communications
AU - Zelenov, Victor Petrovich
AU - Bukalov, Sergei Sergeevich
AU - Subbotin, Alexandr Nikolaevich
PY - 2017
DA - 2017/06/29
PB - Mendeleev Communications
SP - 355-356
IS - 4
VL - 27
ER -
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@article{2017_Zelenov,
author = {Victor Petrovich Zelenov and Sergei Sergeevich Bukalov and Alexandr Nikolaevich Subbotin},
title = {A new type of the dinitrogen pentoxide–acid interaction},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.011},
number = {4},
pages = {355--356},
doi = {10.1016/j.mencom.2017.07.011}
}
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Zelenov, Victor Petrovich, et al. “A new type of the dinitrogen pentoxide–acid interaction.” Mendeleev Communications, vol. 27, no. 4, Jun. 2017, pp. 355-356. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.011.

Abstract

Dinitrogen pentoxide solution in trifluoroacetic acid simultaneously has features of both known types of its interaction with acids, viz. with weak and strong acids. It partially reacts with CF3COOH to give the covalent trifluoroacetyl nitrate and nitric acid, however the major part of N2O5 exists in the covalent form in solution to concurrently produce nitronium ions due to the presence of HNO3. Quantum chemical calculations confirm the equilibrium nature of CF3COOHN2O5 interaction.

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