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Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands

Yuriy Nikolaevich Kononevich 1
Yuriy Nikolaevich Kononevich
, 
Anton Aleksandrovich Anisimov 1
Anton Aleksandrovich Anisimov
, 
Alexander Aleksandrovich Korlyukov 1, 2
Alexander Aleksandrovich Korlyukov
, 
Ul'yana Sergeevna Tsareva 1
Ul'yana Sergeevna Tsareva
, 
Olga Ivanovna Shchegolikhina 1
Olga Ivanovna Shchegolikhina
, 
Aziz Mansurovich Muzafarov 1, 3
Aziz Mansurovich Muzafarov
10.1016/j.mencom.2017.07.002
Published 2017-06-29
Communication , Volume 27, Issue 4, 332-334
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Kononevich Y. N. et al. Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 332-334.
GOST all authors (up to 50) Copy
Kononevich Y. N., Anisimov A. A., Korlyukov A. A., Tsareva U. S., Shchegolikhina O. I., Muzafarov A. M. Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 332-334.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.002
TI - Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands
T2 - Mendeleev Communications
AU - Kononevich, Yuriy Nikolaevich
AU - Anisimov, Anton Aleksandrovich
AU - Korlyukov, Alexander Aleksandrovich
AU - Tsareva, Ul'yana Sergeevna
AU - Shchegolikhina, Olga Ivanovna
AU - Muzafarov, Aziz Mansurovich
PY - 2017
DA - 2017/06/29
PB - Mendeleev Communications
SP - 332-334
IS - 4
VL - 27
ER -
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@article{2017_Kononevich,
author = {Yuriy Nikolaevich Kononevich and Anton Aleksandrovich Anisimov and Alexander Aleksandrovich Korlyukov and Ul'yana Sergeevna Tsareva and Olga Ivanovna Shchegolikhina and Aziz Mansurovich Muzafarov},
title = {Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.002},
number = {4},
pages = {332--334},
doi = {10.1016/j.mencom.2017.07.002}
}
MLA
Cite this
MLA Copy
Kononevich, Yuriy Nikolaevich, et al. “Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands.” Mendeleev Communications, vol. 27, no. 4, Jun. 2017, pp. 332-334. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.002.

Abstract

Two new polyherdal copper metallasiloxanes with pyridine ligands were synthesized by the hydrolysis of triethoxyphenylsilane in the presence of NaOH and the subsequent interaction of the alkaline salt thus in situ formed with CuCl or CuCl2 in pyridine media. Depending on the salt used, tetra- or pentanuclear sandwich-like Cu-metallasiloxanes were obtained, whose structures were studied by single crystal X-ray diffraction.

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