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Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers

Danil Nikolaevich Dybtsev 1, 2
Danil Nikolaevich Dybtsev
, 
Aleksandr Aleksandrovich Sapianik 1
Aleksandr Aleksandrovich Sapianik
, 
Vladimir Petrovich Fedin 1, 2
Vladimir Petrovich Fedin
10.1016/j.mencom.2017.07.001
Published 2017-06-29
Focus article , Volume 27, Issue 4, 321-331
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Dybtsev D. N., Sapianik A. A., Fedin V. P. Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 321-331.
GOST all authors (up to 50) Copy
Dybtsev D. N., Sapianik A. A., Fedin V. P. Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 321-331.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.001
TI - Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers
T2 - Mendeleev Communications
AU - Dybtsev, Danil Nikolaevich
AU - Sapianik, Aleksandr Aleksandrovich
AU - Fedin, Vladimir Petrovich
PY - 2017
DA - 2017/06/29
PB - Mendeleev Communications
SP - 321-331
IS - 4
VL - 27
ER -
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@article{2017_Dybtsev,
author = {Danil Nikolaevich Dybtsev and Aleksandr Aleksandrovich Sapianik and Vladimir Petrovich Fedin},
title = {Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.001},
number = {4},
pages = {321--331},
doi = {10.1016/j.mencom.2017.07.001}
}
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Dybtsev, Danil Nikolaevich, et al. “Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers.” Mendeleev Communications, vol. 27, no. 4, Jun. 2017, pp. 321-331. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.07.001.
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Abstract

The tailored synthesis of periodic coordination structures is fundamentally important for the design of porous compounds with desired functionalities. The building block approach allows a rational and modular design of metal-organic frameworks to be accomplished from the scratch. This concept takes the advantage of the structural robustness and fixed geometry of ligands in the pre-synthesized complexes. Moreover, such a synthetic protocol can lead to otherwise unaccessible coordination structures. This review outlines the examples of the successful creation of metal-organic frameworks from discrete polynuclear complexes. We hope this work will inspire researchers in their everlasting quest for the targeted design of the materials with desired functionalities.

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