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Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene

Vera Vladimirovna Astakhova 1
Vera Vladimirovna Astakhova
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
Bagrat Armenovich Shainyan 1
Bagrat Armenovich Shainyan
Published 2017-04-25
CommunicationVolume 27, Issue 3, 293-295
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Astakhova V. V. et al. Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 293-295.
GOST all authors (up to 50) Copy
Astakhova V. V., Moskalik M. Y., Sterkhova I. V., Shainyan B. A. Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 293-295.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.026
TI - Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene
T2 - Mendeleev Communications
AU - Astakhova, Vera Vladimirovna
AU - Moskalik, Mikhail Yur'evich
AU - Sterkhova, Irina Vladimirovna
AU - Shainyan, Bagrat Armenovich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 293-295
IS - 3
VL - 27
ER -
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@article{2017_Astakhova,
author = {Vera Vladimirovna Astakhova and Mikhail Yur'evich Moskalik and Irina Vladimirovna Sterkhova and Bagrat Armenovich Shainyan},
title = {Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.026},
number = {3},
pages = {293--295},
doi = {10.1016/j.mencom.2017.05.026}
}
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Astakhova, Vera Vladimirovna, et al. “Stereochemistry and mechanism of oxidative 1,4-addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 293-295. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.026.

Abstract

Oxidative addition of trifluoroacetamide to 2,3-dimethylbuta-1,3-diene leads to N,N’-[(2E)-2,3-dimethylbut-2-ene-1,4-diyl]bis(trifluoroacetamide) and [(2RS,3SR)-N-(2,3-dihydroxy-4-iodo-2,3-dimethylbutyl)trifluoroacetamide. A tentative mechanism is proposed.

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