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Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator

Nikita Gennad'evich Sedush 1
Nikita Gennad'evich Sedush
, 
Victor Vladimirovich Izraylit 1
Victor Vladimirovich Izraylit
, 
Arthur Karenovich Mailyan 1, 2
Arthur Karenovich Mailyan
, 
Dmitrii Valer'evich Savinov 1
Dmitrii Valer'evich Savinov
, 
Yury Ivanovich Kiryukhin 1
Yury Ivanovich Kiryukhin
, 
Sergei Nikolaevich Chvalun 1, 3
Sergei Nikolaevich Chvalun
10.1016/j.mencom.2017.05.021
Published 2017-04-25
Communication , Volume 27, Issue 3, 281-282
9
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Sedush N. G. et al. Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 281-282.
GOST all authors (up to 50) Copy
Sedush N. G., Izraylit V. V., Mailyan A. K., Savinov D. V., Kiryukhin Y. I., Chvalun S. N. Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 281-282.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.021
TI - Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator
T2 - Mendeleev Communications
AU - Sedush, Nikita Gennad'evich
AU - Izraylit, Victor Vladimirovich
AU - Mailyan, Arthur Karenovich
AU - Savinov, Dmitrii Valer'evich
AU - Kiryukhin, Yury Ivanovich
AU - Chvalun, Sergei Nikolaevich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 281-282
IS - 3
VL - 27
ER -
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@article{2017_Sedush,
author = {Nikita Gennad'evich Sedush and Victor Vladimirovich Izraylit and Arthur Karenovich Mailyan and Dmitrii Valer'evich Savinov and Yury Ivanovich Kiryukhin and Sergei Nikolaevich Chvalun},
title = {Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.021},
number = {3},
pages = {281--282},
doi = {10.1016/j.mencom.2017.05.021}
}
MLA
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MLA Copy
Sedush, Nikita Gennad'evich, et al. “Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 281-282. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.021.

Abstract

A combination of Zn–guanidine complex catalyst and biphenyl-4-methanol activator was used as a biofriendly system for the synthesis of poly(d,l-lactide). Kinetic curves of the polymerization were measured by differential scanning calorimetry at various temperatures and concentrations of the activator. Due to an inclusion of guanidine ligands into the polymer chains, the synthesized polylactide is capable of fluorescing.

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