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Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV

Vitalii Yur'evich Kotov 1, 2
Vitalii Yur'evich Kotov
, 
Andrei Borisovich Ilyukhin 1
Andrei Borisovich Ilyukhin
, 
Alexey Aleksandrovich Sadovnikov 1
Alexey Aleksandrovich Sadovnikov
, 
Kirill Petrovich Birin 3
Kirill Petrovich Birin
, 
Nikolai Petrovich Simonenko 1
Nikolai Petrovich Simonenko
, 
Hang Thi Nguyen 1
Hang Thi Nguyen
, 
Aleksandr Yevgen'evich Baranchikov 1, 4
Aleksandr Yevgen'evich Baranchikov
, 
Sergei Aleksandrovich Kozyukhin 1
Sergei Aleksandrovich Kozyukhin
10.1016/j.mencom.2017.05.018
Published 2017-04-25
Communication , Volume 27, Issue 3, 271-273
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Kotov V. Y. et al. Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 271-273.
GOST all authors (up to 50) Copy
Kotov V. Y., Ilyukhin A. B., Sadovnikov A. A., Birin K. P., Simonenko N. P., Nguyen H. T., Baranchikov A. Y., Kozyukhin S. A. Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 271-273.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.018
TI - Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV
T2 - Mendeleev Communications
AU - Kotov, Vitalii Yur'evich
AU - Ilyukhin, Andrei Borisovich
AU - Sadovnikov, Alexey Aleksandrovich
AU - Birin, Kirill Petrovich
AU - Simonenko, Nikolai Petrovich
AU - Nguyen, Hang Thi
AU - Baranchikov, Aleksandr Yevgen'evich
AU - Kozyukhin, Sergei Aleksandrovich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 271-273
IS - 3
VL - 27
ER -
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@article{2017_Kotov,
author = {Vitalii Yur'evich Kotov and Andrei Borisovich Ilyukhin and Alexey Aleksandrovich Sadovnikov and Kirill Petrovich Birin and Nikolai Petrovich Simonenko and Hang Thi Nguyen and Aleksandr Yevgen'evich Baranchikov and Sergei Aleksandrovich Kozyukhin},
title = {Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.018},
number = {3},
pages = {271--273},
doi = {10.1016/j.mencom.2017.05.018}
}
MLA
Cite this
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Kotov, Vitalii Yur'evich, et al. “Bis(4-cyano-1-pyridino)pentane halobismuthates. Light-harvesting material with an optical band gap of 1.59 eV.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 271-273. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.018.

Abstract

A new organic-inorganic hybrid material composed of 0-D bromobismuthate anions and bis(4-cyano-1-pyridino)pentane cations was synthesized and characterized. The replacement of Br with I resulted in a decrease in the optical band gap from 2.88 eV for (C17H18N4)2Bi2Br10 to 1.59 eV for (C17H18N4)BiI5. Thus, (C17H18N4)BiI5 can be proposed as a candidate material for solid state solar cells.

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