Home / Publications / Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation

Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation

Ekaterina F Chernova 1, 2
Ekaterina F Chernova
, 
Alexander Sergeevich Ovsyannikov 1, 3
Alexander Sergeevich Ovsyannikov
, 
Sylvie Ferlay 2
Sylvie Ferlay
, 
Svetlana Evgenievna Solovieva 1, 3
Svetlana Evgenievna Solovieva
, 
Igor' Sergeevich Antipin 1, 3
Igor' Sergeevich Antipin
, 
Aleksandr Ivanovich Konovalov 1, 3
Aleksandr Ivanovich Konovalov
, 
Nathalie Kyritsakas 2
Nathalie Kyritsakas
, 
Mir Wais Hosseini 2
Mir Wais Hosseini
10.1016/j.mencom.2017.05.014
Published 2017-04-25
Communication , Volume 27, Issue 3, 260-262
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Chernova E. F. et al. Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 260-262.
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Chernova E. F., Ovsyannikov A. S., Ferlay S., Solovieva S. E., Antipin I. S., Konovalov A. I., Kyritsakas N., Hosseini M. W. Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 260-262.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.014
TI - Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation
T2 - Mendeleev Communications
AU - Chernova, Ekaterina F
AU - Ovsyannikov, Alexander Sergeevich
AU - Ferlay, Sylvie
AU - Solovieva, Svetlana Evgenievna
AU - Antipin, Igor' Sergeevich
AU - Konovalov, Aleksandr Ivanovich
AU - Kyritsakas, Nathalie
AU - Hosseini, Mir Wais
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 260-262
IS - 3
VL - 27
ER -
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@article{2017_Chernova,
author = {Ekaterina F Chernova and Alexander Sergeevich Ovsyannikov and Sylvie Ferlay and Svetlana Evgenievna Solovieva and Igor' Sergeevich Antipin and Aleksandr Ivanovich Konovalov and Nathalie Kyritsakas and Mir Wais Hosseini},
title = {Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.014},
number = {3},
pages = {260--262},
doi = {10.1016/j.mencom.2017.05.014}
}
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Chernova, Ekaterina F., et al. “Molecular tectonics: from a binuclear metallamacrocycle to a 1D isostructural coordination network based on tetracyanomethyl[1.1.1.1]metacyclophane and a silver cation.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 260-262. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.014.
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Abstract

Depending on the anion (NO3- or BF4-) and stoichiometry, the combinations of [1.1.1.1]metacyclophane adopting a blocked 1,3-alternate conformation and bearing four cyanomethylene groups with silver cations under self-assembly conditions lead to the formation of either a 1D coordination network or a discrete binuclear metallomacrocycle.

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