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Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen

Evgenii Moiseevich Pliss 1
Evgenii Moiseevich Pliss
, 
Aleksei Mikhailovich Grobov 1
Aleksei Mikhailovich Grobov
, 
Anton K Kuzaev 1
Anton K Kuzaev
, 
Anatolii Leonidovich Buchachenko 1, 2, 3
Anatolii Leonidovich Buchachenko
10.1016/j.mencom.2017.05.009
Published 2017-04-25
Communication , Volume 27, Issue 3, 246-247
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Pliss E. M. et al. Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 246-247.
GOST all authors (up to 50) Copy
Pliss E. M., Grobov A. M., Kuzaev A. K., Buchachenko A. L. Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 246-247.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.009
TI - Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen
T2 - Mendeleev Communications
AU - Pliss, Evgenii Moiseevich
AU - Grobov, Aleksei Mikhailovich
AU - Kuzaev, Anton K
AU - Buchachenko, Anatolii Leonidovich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 246-247
IS - 3
VL - 27
ER -
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@article{2017_Pliss,
author = {Evgenii Moiseevich Pliss and Aleksei Mikhailovich Grobov and Anton K Kuzaev and Anatolii Leonidovich Buchachenko},
title = {Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.009},
number = {3},
pages = {246--247},
doi = {10.1016/j.mencom.2017.05.009}
}
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Pliss, Evgenii Moiseevich, et al. “Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 246-247. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.009.

Abstract

Magnetic fields (0.3–0.4 T) were found to accelerate the oxidation of styrene and ethylbenzene with molecular oxygen by 10–70% with increasing the rate of initiation and decreasing the rate of chain termination. The effects are consistently explained in terms of triplet–singlet spin conversion in radical pairs, and they can be used to elucidate the oxidation mechanisms of biologically important molecules (polyunsaturated acids and lipids).

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