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Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene

Ilgiz Maratovich Biktagirov 1
Ilgiz Maratovich Biktagirov
, 
Liliya Khalitovna Faizullina 1
Liliya Khalitovna Faizullina
, 
Shamil Mubarakovich Salikhov 1
Shamil Mubarakovich Salikhov
, 
Fanur Zufarovich Galin 1
Fanur Zufarovich Galin
, 
Farid Abdullovich Valeev 1
Farid Abdullovich Valeev
10.1016/j.mencom.2017.05.006
Published 2017-04-25
Communication , Volume 27, Issue 3, 237-239
3
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Biktagirov I. M. et al. Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 237-239.
GOST all authors (up to 50) Copy
Biktagirov I. M., Faizullina L. K., Salikhov S. M., Galin F. Z., Valeev F. A. Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 237-239.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.006
TI - Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene
T2 - Mendeleev Communications
AU - Biktagirov, Ilgiz Maratovich
AU - Faizullina, Liliya Khalitovna
AU - Salikhov, Shamil Mubarakovich
AU - Galin, Fanur Zufarovich
AU - Valeev, Farid Abdullovich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 237-239
IS - 3
VL - 27
ER -
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@article{2017_Biktagirov,
author = {Ilgiz Maratovich Biktagirov and Liliya Khalitovna Faizullina and Shamil Mubarakovich Salikhov and Fanur Zufarovich Galin and Farid Abdullovich Valeev},
title = {Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.006},
number = {3},
pages = {237--239},
doi = {10.1016/j.mencom.2017.05.006}
}
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Biktagirov, Ilgiz Maratovich, et al. “Photochemical rearrangement of 5,6-epoxy derivatives of the Diels–Alder adduct of levoglucosenone and piperylene.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 237-239. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.006.

Abstract

Photolysis of 5,6-epoxy 4-keto derivatives of the Diels–Alder adduct of levoglucosenone and piperylene in C6H6–MeOH causes cleavage of the C4–C5 bond giving product containing vicinal acetone and alkyl acetate moieties, the latter would further transform into 1-alkoxycarbonyl-2-hydroxy-2-methylcyclopentane derivative annulated to 5,8-dioxabicyclo[3.2.1]octane cage.

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