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A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety

Vladimir Anatol'evich D'yakonov 1
Vladimir Anatol'evich D'yakonov
, 
Aleksey Aleksandrovich Makarov 1
Aleksey Aleksandrovich Makarov
, 
Alfiya Raisovna Salimova 1
Alfiya Raisovna Salimova
, 
Evgeny Nazarovich Andreev 1
Evgeny Nazarovich Andreev
, 
10.1016/j.mencom.2017.05.005
Published 2017-04-25
Communication , Volume 27, Issue 3, 234-236
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D'yakonov V. A. et al. A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 234-236.
GOST all authors (up to 50) Copy
D'yakonov V. A., Makarov A. A., Salimova A. R., Andreev E. N., Dzhemilev U. M. A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 234-236.
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TY - JOUR
DO - 10.1016/j.mencom.2017.05.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.005
TI - A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety
T2 - Mendeleev Communications
AU - D'yakonov, Vladimir Anatol'evich
AU - Makarov, Aleksey Aleksandrovich
AU - Salimova, Alfiya Raisovna
AU - Andreev, Evgeny Nazarovich
AU - Dzhemilev, Usein Memetovich
PY - 2017
DA - 2017/04/25
PB - Mendeleev Communications
SP - 234-236
IS - 3
VL - 27
ER -
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@article{2017_D'yakonov,
author = {Vladimir Anatol'evich D'yakonov and Aleksey Aleksandrovich Makarov and Alfiya Raisovna Salimova and Evgeny Nazarovich Andreev and Usein Memetovich Dzhemilev},
title = {A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.005},
number = {3},
pages = {234--236},
doi = {10.1016/j.mencom.2017.05.005}
}
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D'yakonov, Vladimir Anatol'evich, et al. “A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety.” Mendeleev Communications, vol. 27, no. 3, Apr. 2017, pp. 234-236. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2017.05.005.

Abstract

Natural (5Z,9Z)-dienoic acids and key precursors of biologically active trienoic acids were prepared in high yields and with high stereoselectivity using cross-cyclomagnesiation of terminal and oxygenated 1,2-dienes with EtMgBr in the presence of Mg metal and Cp2TiCl2 catalyst at the key step.

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